3-Chloro-benzoic acid (3S,4S,6aR,6bS,8aS,9R,10S,12aS,12bS,14aS,14bS)-10-acetoxy-3-hydroxy-2,2,5,6a,8a,9,12b,14a-octamethyl-1,2,3,4,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14,14a,14b-icosahydro-picen-4-yl ester | 80179-06-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 3-Chloro-benzoic acid (3S,4S,6aR,6bS,8aS,9R,10S,12aS,12bS,14aS,14bS)-10-acetoxy-3-hydroxy-2,2,5,6a,8a,9,12b,14a-octamethyl-1,2,3,4,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14,14a,14b-icosahydro-picen-4-yl ester
• CAS: 80179-06-2
• 化学式: C₃₉H₅₅ClO₅
• 分子量: 639.316
• InChiKey: GTDBWKRYUOSQOP-ROCNHNBRSA-N

反应信息

• 作为反应物：
  描述：

  3-Chloro-benzoic acid (3S,4S,6aR,6bS,8aS,9R,10S,12aS,12bS,14aS,14bS)-10-acetoxy-3-hydroxy-2,2,5,6a,8a,9,12b,14a-octamethyl-1,2,3,4,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14,14a,14b-icosahydro-picen-4-yl ester 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 反应 2.0h， 以11 mg的产率得到(3S,4S,6aR,6bS,8aS,9R,10S,12aS,12bS,14aS,14bS)-2,2,5,6a,8a,9,12b,14a-Octamethyl-1,2,3,4,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14,14a,14b-icosahydro-picene-3,4,10-triol
  参考文献：
  名称：

  Kikuchi, Tohru; Yokoi, Toshio; Shingu, Tetsuro, Chemical and pharmaceutical bulletin, 1981, vol. 29, # 9, p. 2531 - 2539

  摘要：

  DOI：
• 作为产物：
  描述：

  pachysandienol-A acetate 、 间氯过氧苯甲酸 以 苯 为溶剂， 以20 mg的产率得到3-Chloro-benzoic acid (3S,4S,6aR,6bS,8aS,9R,10S,12aS,12bS,14aS,14bS)-10-acetoxy-3-hydroxy-2,2,5,6a,8a,9,12b,14a-octamethyl-1,2,3,4,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14,14a,14b-icosahydro-picen-4-yl ester
  参考文献：
  名称：

  Kikuchi, Tohru; Yokoi, Toshio; Shingu, Tetsuro, Chemical and pharmaceutical bulletin, 1981, vol. 29, # 9, p. 2531 - 2539

  摘要：

  DOI：