| 1356329-92-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噁庚英
• CAS: 1356329-92-4
• 化学式: C₄₈H₄₂N₉O₆P₃
• 分子量: 933.839
• InChiKey: SYUMVARGAPJTCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.87
• 重原子数：
  66.0
• 可旋转键数：
  0.0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  166.62
• 氢给体数：
  0.0
• 氢受体数：
  15.0

反应信息

• 作为产物：
  描述：

  六氯环三磷腈 、 N,N'-双(亚水杨基)乙二胺 在 Al₂O₃/KOH 作用下， 以 甲苯 为溶剂， 反应 2.0h， 以86%的产率得到
  参考文献：
  名称：

  Synthesis of new derivatives of cyclotriphosphazene substituted with the salen side groups

  摘要：

  The reaction between hexachlorocyclotriphosphazenes (N(3)P(3)Cl(6)) and three equivalents of bis-salicylidene ethylene diamine (HOC(6)H(4)-CH=N-CH(2)-)(2) (salen) was investigated in two different experimental conditions. In the presence of anhydrous Na(2)CO(3) in stirring tetrahydrofuran (THF) medium, the reaction led to a 50:50 mixture of tris[bis(salicylidene)ethylenediamine] cyclotriphosphazene, spiro-N(3)P(3)[(OC(6)H(4)-CH=N-CH(2-))(2)](3) (1) and ansa (2) fully substituted products, whereas, in toluene solution, N(3)P(3)Cl(6) with salen (3) and Al(2)O(3)/KOH afforded the spiro (1), as the only isolable compound. The spectroscopic data revealed that the oxygen atoms of salen moieties were selectively bonded to the three phosphorus atoms of the phosphazene ring. The new derivatives of cyclotriphosphazenes were characterized by IR spectrophotometry (1)H NMR, (31)P NMR spectral data and elemental analysis.

  DOI：

  10.1007/bf03246557