all-cis,tris-endo-N,N'-N"-tris-(n-butyl)tricyclo<5.2.1.0^4,10>decan-2,5,8-triamine | 136869-69-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: all-cis,tris-endo-N,N'-N"-tris-(n-butyl)tricyclo<5.2.1.0^4,10>decan-2,5,8-triamine
• CAS: 136869-69-7
• 化学式: C₂₂H₄₃N₃
• 分子量: 349.604
• InChiKey: WKHMDLGIEDHMPY-KZTWIJCSSA-N

反应信息

• 作为产物：
  描述：

  Cyclopenta[cd]pentalene-1,3,5(2H)-trione, hexahydro- 、 正丁胺 在 10% palladium on active carbon 氢气 作用下， 以 甲醇 为溶剂， 反应 24.0h， 以72%的产率得到all-cis,tris-endo-N,N'-N"-tris-(n-butyl)tricyclo<5.2.1.0^4,10>decan-2,5,8-triamine
  参考文献：
  名称：

  Perhydrotriquinacenic hosts. 1. Synthesis, complexation and transport properties of tripodands of C3 symmetry.

  摘要：

  A general strategy for the synthesis of tripodands of C3 symmetry, which involves the reductive amination of tricyclo[5.2.1.0(4),10]decane-2,5,8-trione 1, is described. Preliminary studies show that these tripodands exhibit complexation and transport properties similar to those of previously described podands.

  DOI：

  10.1016/s0040-4020(01)86537-6