4,4',4''-(ethane-1,1,2-triyl)tris(bromobenzene) | 111561-90-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 4,4',4''-(ethane-1,1,2-triyl)tris(bromobenzene)
• 英文别名: 4,4',4''-(ethene-1,1,2-triyl)tris(bromobenzene)；tris-(4-bromo-phenyl)-ethene；Tris-(4-brom-phenyl)-aethen；1-[1,2-Bis(4-bromophenyl)ethenyl]-4-bromobenzene
• CAS: 111561-90-1
• 化学式: C₂₀H₁₃Br₃
• 分子量: 493.035
• InChiKey: OBQPOLFLFVKACY-UHFFFAOYSA-N

物化性质

• 熔点：
  101 °C
• 沸点：
  255-265 °C(Press: 0.3 Torr)
• 密度：
  1.714±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  4,4',4''-(ethane-1,1,2-triyl)tris(bromobenzene) 在 溴 作用下， 生成 bromo-tris-(4-bromo-phenyl)-ethene
  参考文献：
  名称：

  Influences of support fibers on shapes of heptane/hexadecane droplets in reduced gravity

  摘要：

  This paper describes analytical and experimental results related to the effects of support fibers on shapes of heptane/hexadecane mixture droplets (both burning and evaporating) in reduced gravity. The experimental results were obtained from large droplets (a few mm) investigated during the MSL-1 Flight of Spacelab. Theoretical (asymptotic) analyses are developed to predict droplet shapes. These analyses, which predict droplet shapes very well, illustrate important aspects of droplet shapes in a transparent fashion. The asymptotic theory shows that for small droplet-fiber contact angles, two spatial zones exist where droplet shapes behave differently. Away from a fiber a droplet is essentially spherical. As the fiber is approached, however deviations from spherical symmetry are significant. Previously developed analytical theory to predict macroscopic droplet shapes also compares well with experimental results. In addition, the experiments indicate that thin liquid films can form on support fibers. In the present experiments, these films apparently lead to transient formation of small droplets/bubbles on the support fibers at locations near the surface of a droplet.

  DOI：

  10.1007/bf02881679
• 作为产物：
  描述：

  对溴溴苄 在 potassium tert-butylate 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 生成 4,4',4''-(ethane-1,1,2-triyl)tris(bromobenzene)
  参考文献：
  名称：

  Detecting live bacteria instantly utilizing AIE strategies

  摘要：

  一种新型的生物传感器分子被研究，通过限制旋转与细菌结合来引发荧光发射，以检测活细菌的适用性。

  DOI：

  10.1039/c8tb01390j

文献信息

• Palladium-catalyzed double arylations of terminal olefins in acetic acid
  作者：Daichao Xu、Chunxin Lu、Wanzhi Chen

  DOI：10.1016/j.tet.2011.12.017

  日期：2012.2

  A palladium-catalyzed Heck diarylation of terminal olefins under ligand-free conditions in acetic acid is described. This procedure allows double arylation of terminal olefins affording trisubstituted olefins in good to excellent yields. The methodology is applicable to the coupling of both electron-deficient and electron-rich aryl iodides leading to symmetrical and unsymmetrical β,β-diarylated alkenes

  描述了在无配体条件下在乙酸中钯催化的末端烯烃的Heck二芳基化。该方法允许末端烯烃进行双芳基化，从而以良好至优异的产率提供三取代的烯烃。该方法适用于缺电子和富电子的芳基碘化物的偶合，从而导致对称和不对称的β，β-二芳基化烯烃。
• Unexpected and powerful effect of chlorobenzene in direct palladium-catalyzed cascade Sonogashira–hydroarylation reaction
  作者：Bo Yu、Wei Xu、Huaming Sun、Binxun Yu、Guofang Zhang、Li-Wen Xu、Weiqiang Zhang、Ziwei Gao

  DOI：10.1039/c4ra13979h

  日期：——

  (PhCl) was observed unexpectedly in the Pd-catalyzed cascade Sonogashira–hydroarylation reaction. This new type of carbon–carbon bond forming cross-coupling reaction was efficiently catalysed by Pd2(dba)3 in the presence of a catalytic amount of PhCl, which provides a facile and direct approach to the synthesis of trisubstituted olefins.

  在Pd催化的级联Sonogashira-加氢芳基化反应中出乎意料地观察到了氯苯（PhCl）的普遍加速作用。在催化量的PhCl存在下，Pd 2（dba）3有效地催化了这种新型的碳-碳键形成交叉偶联反应，这为三取代烯烃的合成提供了一种简便而直接的方法。
• Piezofluorochromic and Aggregation-Induced-Emission Compounds Containing Triphenylethylene and Tetraphenylethylene Moieties
  作者：Bingjia Xu、Zhenguo Chi、Jianyong Zhang、Xiqi Zhang、Haiyin Li、Xiaofang Li、Siwei Liu、Yi Zhang、Jiarui Xu

  DOI：10.1002/asia.201100211

  日期：2011.6.6

  New fluorescent compounds containing triphenylethylene and tetraphenylethylene moieties were synthesized, and their piezofluorochromic and aggregation‐induced emission behaviors were investigated. The results show that all compounds exhibit aggregation‐induced emission characteristics and only the crystalline compound possesses piezofluorochromic properties. The color, emission spectra, and morphological

  合成了包含三苯基乙烯和四苯基乙烯部分的新型荧光化合物，并研究了它们的压电荧光致变色和聚集诱导的发射行为。结果表明，所有化合物均表现出聚集诱导的发射特性，仅结晶化合物具有压电氟致变色性质。一种压电氟致变色化合物的颜色，发射光谱和形态结构在研磨和退火（或发烟）处理后表现出可逆性。压电致变色行为是由外部压力下固态分子堆积的不同模式之间的变化引起的。单晶X射线衍射分析表明，聚集体诱导的发射化合物的扭曲构象导致形成具有腔的亚稳晶格，该晶格在外压下很容易被破坏。已经提出了一种可能的压电氟致变色现象的机理。
• 一种乙烯基共轭三芳胺类电荷传输材料及其 制备方法
  申请人：中山大学

  公开号：CN106905169B

  公开（公告）日：2019-02-22

  本发明公开了一种乙烯基共轭三芳胺类电荷传输材料及其制备方法。所述乙烯基共轭三芳胺类电荷传输材料的化学结构式如式（I）所示：本发明所述新型电荷传输材料制备所利用的原料成本低廉，所用的合成方法简单、方便，所合成的材料经过光物理性质（紫外、荧光）测试、电化学性能测试和热稳定性测试，表明电荷传输材料的性能良好，有着优良的热稳定性，能级可以与钙钛矿材料相匹配，可应用于钙钛矿太阳能电池。
• Facile synthesis of a new class of aggregation-induced emission materials derived from triphenylethylene
  作者：Bingjia Xu、Zhenguo Chi、Zhiyong Yang、Jingbo Chen、Shaozhi Deng、Haiyin Li、Xiaofang Li、Yi Zhang、Ningsheng Xu、Jiarui Xu

  DOI：10.1039/c0jm00229a

  日期：——

  A series of new aggregation-induced emission compounds with strong blue light-emitting properties derived from triphenylethylene were facilely synthesized by a Wittig–Horner reaction of bis(4-bromophenyl)methanone with diethyl 4-bromobenzylphosphonate, followed by a Suzuki reaction with arylboronic acids. Their maximum fluorescence emission wavelengths were 452–462 nm. The glass transition temperatures ranged from 70–145 °C, and the decomposition temperatures were 360–508 °C. The unoptimized device fabricated with benzofuranyl substituted compound as emitter turned on at ∼6 V, and the maximum luminance was ∼1500 cd m−2.

  通过双(4-溴苯基)甲酮与4-溴苄基膦酸二乙酯的Wittig-Horner反应，然后与芳基硼酸进行Suzuki反应，轻松合成了一系列源自三苯乙烯的具有强蓝光发射特性的新型聚集诱导发光化合物。它们的最大荧光发射波长为 452–462 nm。玻璃化转变温度范围为70-145°C，分解温度为360-508°C。使用苯并呋喃基取代的化合物作为发射极制造的未经优化的器件在〜6 V时开启，最大亮度为〜1500 cd m−2。