4,6,11-三氧杂-1-氮杂-5-铋杂双环[3.3.3]十一烷 | 26151-44-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 4,6,11-三氧杂-1-氮杂-5-铋杂双环[3.3.3]十一烷
• 英文名称: [Bi(triethanolaminolate)]n
• 英文别名: [Bi(tea)]n；Bismuth;2-[bis(2-oxidoethyl)amino]ethanolate；bismuth;2-[bis(2-oxidoethyl)amino]ethanolate
• CAS: 26151-44-0；283-55-6
• 化学式: Bi*C₆H₁₂NO₃
• 分子量: 355.147
• InChiKey: AYZOYIDAUUFAAL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.65
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  30.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4,6,11-三氧杂-1-氮杂-5-铋杂双环[3.3.3]十一烷 以 neat (no solvent, solid phase) 为溶剂， 生成 bismuth(III) oxide
  参考文献：
  名称：

  Bismuth ladder polymers: structural and thermal studies of [Bi(OCH2CH2)3N]n and [(BixTb1−x(O2C2H2)3N·2H2O]n

  摘要：

  [Bi(OCH2CH2)(3)N],(Bi(TEA)), may be prepared by reaction of in situ generated Bi(OH)(3) with triethanolamine in refluxing methanol. The complex crystallizes from solution as a double ladder polymer via the formation of additional metal-oxygen dative bonds to yield hypercoordinate and hypervalent metal centers. The structure of Bi(TEA) is very similar to that of Bi(O2CCH3)(3)N. The heterobimetallic nitriloacetate complex containing Bi and Tb was prepared by reaction of (NH4)(3)[Bi(Nta)(2)] with terbium nitrate in aqueous solution. Heating samples of [Bi(OCH2CH2)(3)N](n) to 1000 degreesC results in the formation of Bi2O3. It was shown that thermolysis of the [(BixTb1-x(O2C2H2)(3)N).H2O](n) occurs in two stages, viz. the deaquation and pyrolysis of the ligand. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01381-6
• 作为产物：
  描述：

  三乙醇胺 、 bismuth(III) oxide 以 甲苯 为溶剂， 以87%的产率得到4,6,11-三氧杂-1-氮杂-5-铋杂双环[3.3.3]十一烷
  参考文献：
  名称：

  从氧化铋中经济高效地合成氨基醇铋：[Bi2(mdea)2(mdeaH)2](mdeaH2)2 的分子结构

  摘要：

  摘要 将氧化物与N-甲基二乙醇胺(mdeaH2)、二乙醇胺(deaH2)、三乙醇胺(teaH3)等二元醇在回流甲苯中高产率反应制备功能性双醇盐。与没有 N 供体位点的多元醇的类似反应会产生含氧物种。用 N-甲基二乙醇胺获得的衍生物通过 X 射线衍射表征为二聚体 [Bi2(mdea)2(mdeaH)2]，通过 H 键与中性二醇分子结合成链，得到标题化合物。铋是伪 7 坐标。Bi-O 键距范围从 2.150(5) 到 3.093(5) A，具有三个短键，而跨环 Bi-N 键距为 2.737 A av。报道了热解和水解反应。

  DOI：

  10.1016/j.inoche.2006.09.012

文献信息

• Low temperature and controlled synthesis of Bi₂(S_1−xSe_x)₃ thin films using a simple chemical route: effect of bath composition
  作者：Manauti M. Salunkhe、Kishorkumar V. Khot、Sanjay H. Sahare、Popatrao N. Bhosale、Tejashree Bhave

  DOI：10.1039/c5ra07372c

  日期：——

  Nanostructured Bi₂(S_1−xSe_x)₃ thin films were synthesized using a simple chemical bath deposition method at room temperature, and their photoelectrochemical performance was tested.

  使用简单的化学浴沉积方法在室温下合成了纳米结构的Bi₂(S_1−xSe_x)₃薄膜，并测试了它们的光电化学性能。
• Cost efficient synthesis of bismuth aminoalkoxides from bismuth oxide: Molecular structure of [Bi2(mdea)2(mdeaH)2](mdeaH2)2
  作者：Jérome Le Bris、Liliane G. Hubert-Pfalzgraf、Stéphane Daniele、Jacqueline Vaissermann

  DOI：10.1016/j.inoche.2006.09.012

  日期：2007.1

  Abstract Functional Bi alkoxides were prepared by reaction between the oxide and diols such as N-methyldiethanolamine (mdeaH2), diethanolamine (deaH2) and triethanolamine (teaH3) in refluxing toluene in high yields. Similar reactions with polyols without N-donor site lead to oxo species. The derivative obtained with N-methyldiethanolamine was characterised by X-ray diffraction as a dimer [Bi2(mdea)2(mdeaH)2]

  摘要 将氧化物与N-甲基二乙醇胺(mdeaH2)、二乙醇胺(deaH2)、三乙醇胺(teaH3)等二元醇在回流甲苯中高产率反应制备功能性双醇盐。与没有 N 供体位点的多元醇的类似反应会产生含氧物种。用 N-甲基二乙醇胺获得的衍生物通过 X 射线衍射表征为二聚体 [Bi2(mdea)2(mdeaH)2]，通过 H 键与中性二醇分子结合成链，得到标题化合物。铋是伪 7 坐标。Bi-O 键距范围从 2.150(5) 到 3.093(5) A，具有三个短键，而跨环 Bi-N 键距为 2.737 A av。报道了热解和水解反应。
• Bismuth ladder polymers: structural and thermal studies of [Bi(OCH2CH2)3N]n and [(BixTb1−x(O2C2H2)3N·2H2O]n
  作者：Robert E. Bachman、Kenton H. Whitmire、John H. Thurston、Aurelian Gulea、Olexa Stavila、Vitalie Stavila

  DOI：10.1016/s0020-1693(02)01381-6

  日期：2003.3

  [Bi(OCH2CH2)(3)N],(Bi(TEA)), may be prepared by reaction of in situ generated Bi(OH)(3) with triethanolamine in refluxing methanol. The complex crystallizes from solution as a double ladder polymer via the formation of additional metal-oxygen dative bonds to yield hypercoordinate and hypervalent metal centers. The structure of Bi(TEA) is very similar to that of Bi(O2CCH3)(3)N. The heterobimetallic nitriloacetate complex containing Bi and Tb was prepared by reaction of (NH4)(3)[Bi(Nta)(2)] with terbium nitrate in aqueous solution. Heating samples of [Bi(OCH2CH2)(3)N](n) to 1000 degreesC results in the formation of Bi2O3. It was shown that thermolysis of the [(BixTb1-x(O2C2H2)(3)N).H2O](n) occurs in two stages, viz. the deaquation and pyrolysis of the ligand. (C) 2002 Elsevier Science B.V. All rights reserved.