{3-[Di(prop-2-en-1-yl)amino]prop-2-en-1-ylidene}propanedinitrile | 78339-24-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: {3-[Di(prop-2-en-1-yl)amino]prop-2-en-1-ylidene}propanedinitrile
• 英文别名: 2-[3-[bis(prop-2-enyl)amino]prop-2-enylidene]propanedinitrile
• CAS: 78339-24-9
• 化学式: C₁₂H₁₃N₃
• 分子量: 199.25
• InChiKey: CJQXWEFOWVFNKD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  50.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  {3-[Di(prop-2-en-1-yl)amino]prop-2-en-1-ylidene}propanedinitrile 、 Vinyloxazolidone 在 乙醚 、 N,N-二甲基甲酰胺 、 product 、 水 、 Aminoallylidenmalononitrile 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 24.0h， 生成 Vinyloxazolidone diallylaminoallylidenmalononitrile
  参考文献：
  名称：

  Silver halide photographic emulsions including dye sensitizers and

  摘要：

  本发明的对象是包括银卤化物晶粒分散在明胶中的照相乳剂，以及至少一个甲烷染料光谱增感剂与所述晶粒相关联，包括与其相关联的具有氨基烯丙基丙烯腈基团的聚合物化合物的超增感或稳定化量。本发明还涉及包括所述乳剂的照相元素，特别是放射性成像元素。根据本发明，所述聚合物化合物是通过将包括上述氨基烯丙基丙烯腈基团的烯丙基单体与乙烯基不饱和单体共聚合而得到的。

  公开号：

  US04307183A1

文献信息

• Photographic elements containing polymers having
  申请人：Minnesota Mining and Manufacturing Company

  公开号：US04307184A1

  公开（公告）日：1981-12-22

  The present invention refers to a photographic material including in one of its layers a polymeric product having an aminoallylidenemalononitrile ultraviolet absorber unit which can be introduced into a photographic layer by aqueous solutions, with the method according to this invention, of including said aminoallylidenemalononitrile unit in an allyl monomer and then copolymerizing it with an ethylenically unsaturated monomer in order to obtain said polymeric product to be added to the layer forming composition. This invention is of particular industrial interest in the field of color photographic materials.

  本发明涉及一种摄影材料，其中的一层包含一种聚合物产品，其具有能够通过水溶液引入摄影层的氨基烯丙基丙烯腈紫外线吸收剂单元。根据本发明的方法，将该氨基烯丙基丙烯腈单元包含在烯丙基单体中，然后与乙烯基不饱和单体共聚合，以获得所述聚合物产品以添加到层形成组成物中。本发明在彩色摄影材料领域具有特殊的工业兴趣。
• Silver halide photographic emulsions including dye sensitizers and supersensitizing or stabilizing amounts of a polymeric compound, and photographic elements, particularly radiographic elements, including said emulsions
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0027259A1

  公开（公告）日：1981-04-22

  Object of the invention are photographic emulsions including silver halide grains dispersed in gelatin and at least a methine dye spectral sensitizer associated with said grains, including in association therewith a supersensitizing orstabil- izing amount of polymeric compound having an aminoallylidenmalononitrile moiety. The invention further relates to photographic elements, in particular radiographic elements, comprising said emulsions. According to the invention, said polymeric compound is obtained upon copolymerization of an allyl monomer, comprising said aminoallylidenmalononitrile moiety, with an ethylenically unsaturated monomer.

  本发明的目的是照相乳剂，包括分散在明胶中的卤化银颗粒和至少一种与所述颗粒相关联的亚甲基染料光谱感光剂，包括与之相关联的具有氨基烯丙基丙二腈分子的超感光或稳定量的聚合化合物。本发明还涉及包含所述乳剂的照相元件，特别是射线照相元件。根据本发明，烯丙基单体与乙烯基不饱和单体共聚后可得到上述聚合物。
• 3-Aminoallylidenemalononitrile uv-absorbing compounds and photographic elements containing them
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0210409A2

  公开（公告）日：1987-02-04

  3-Aminoallylidenemalononitrile compounds corresponding to the formula: wherein R, is a short alkyl chain having 1 to 3 carbon atoms and R is a substituted or unsubstituted long alkyl chain greater than 10 carbon atoms, are useful in photography for absorbing ultraviolet radiations in the range from 360 to 400 nm, with no undesired absorption near 420 nm, when introduced in a photographic gelatin layer.

  3-Aminoallylidenemalononitrile 化合物的化学式如下：其中 R 是具有 1 至 3 个碳原子的短烷基链，R 是大于 10 个碳原子的取代或未取代的长烷基链，当引入摄影明胶层时，可用于吸收 360 至 400 纳米范围内的紫外线辐射，而在 420 纳米附近没有不希望的吸收。
• Polymeric ultraviolet absorbers, photographic material including them, and process
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0027242B1

  公开（公告）日：1985-01-02
• Flüssige 2-(2-Hydroxy-3-höherverzweigtalkyl-5-methylphenyl)-2H-benztriazolgemische, Verfahren zu deren Herstellung und diese enthaltende stabilisierte Zusammensetzungen
  申请人：CIBA-GEIGY AG

  公开号：EP0189374B1

  公开（公告）日：1992-03-18