2,3-bis(2-methyl-benzo[b]thiophene-3-yl)-benzo[b]thiophene | 140898-78-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 2,3-bis(2-methyl-benzo[b]thiophene-3-yl)-benzo[b]thiophene
• 英文别名: 2,3-Bis(2-methyl-1-benzothiophen-3-yl)-1-benzothiophene
• CAS: 140898-78-8
• 化学式: C₂₆H₁₈S₃
• 分子量: 426.627
• InChiKey: WXUPGULDUYDMGC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  29
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  84.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,3-bis(2-methyl-benzo[b]thiophene-3-yl)-benzo[b]thiophene 以 正己烷 为溶剂， 生成
  参考文献：
  名称：

  The considerable photostability improvement of photochromic terarylene by sulfone group

  摘要：

  Photochromic terarylene derivative 4 which has a sulfone group at the upper benzothiophene ring is readily synthesized using Suzuki coupling reaction. It exhibits good photochromic properties. Interestingly, the closed form of the compound 4 shows a good photostability as well as a thermal stability compared with its reduced analog 3, that provides a method to enhance the photostability of versatile photochromic terarylenes under UV. (c) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.07.028
• 作为产物：
  描述：

  2,3-二溴苯并[b]噻吩 、 dibutyl(2-methyl-benzo[b]thiophen-3-yl) borane 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 水 为溶剂， 生成 2,3-bis(2-methyl-benzo[b]thiophene-3-yl)-benzo[b]thiophene
  参考文献：
  名称：

  The considerable photostability improvement of photochromic terarylene by sulfone group

  摘要：

  Photochromic terarylene derivative 4 which has a sulfone group at the upper benzothiophene ring is readily synthesized using Suzuki coupling reaction. It exhibits good photochromic properties. Interestingly, the closed form of the compound 4 shows a good photostability as well as a thermal stability compared with its reduced analog 3, that provides a method to enhance the photostability of versatile photochromic terarylenes under UV. (c) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.07.028