1-trimethylsilyl-2-trimethylsiloxyindene | 207848-39-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: 1-trimethylsilyl-2-trimethylsiloxyindene
• CAS: 207848-39-3
• 化学式: C₁₅H₂₄OSi₂
• 分子量: 276.526
• InChiKey: MLQOJOBLFOVXDT-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  四氯化钛 、 1-trimethylsilyl-2-trimethylsiloxyindene 以 二氯甲烷 为溶剂， 以28%的产率得到(2-trimethylsiloxyindenyl)trichlorotitanium
  参考文献：
  名称：

  Siloxy-substituted tetramethylcyclopentadienyl and indenyl trichlorotitanium complexes for syndiospecific polymerization of styrene

  摘要：

  (eta(5)-trimethylsiloxytetramethylcyclopentadienyl)- and (eta(5)-2- trimethylsiloxyindenyl)trichloro titanium have been synthesized and characterized. Their catalytic behavior for the polymerization of styrene was studied in the presence of methylaluminoxane (MAO) as a cocatalyst. They show only low activity for styrene polymerization. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00388-x
• 作为产物：
  描述：

  三甲基氯硅烷 、 2-茚酮 在 lithium diisopropyl amide 作用下， 生成 1-trimethylsilyl-2-trimethylsiloxyindene
  参考文献：
  名称：

  Siloxy-substituted tetramethylcyclopentadienyl and indenyl trichlorotitanium complexes for syndiospecific polymerization of styrene

  摘要：

  (eta(5)-trimethylsiloxytetramethylcyclopentadienyl)- and (eta(5)-2- trimethylsiloxyindenyl)trichloro titanium have been synthesized and characterized. Their catalytic behavior for the polymerization of styrene was studied in the presence of methylaluminoxane (MAO) as a cocatalyst. They show only low activity for styrene polymerization. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00388-x