1,7-dipyrrolidinyl-perylene-9,10-(N-butyl)-dicarboxyimide-3,4-dicarboxylic anhydride | 1380497-11-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并吡喃类
• 英文名称: 1,7-dipyrrolidinyl-perylene-9,10-(N-butyl)-dicarboxyimide-3,4-dicarboxylic anhydride
• CAS: 1380497-11-9
• 化学式: C₃₆H₃₁N₃O₅
• 分子量: 585.659
• InChiKey: KTABPOGGKJHYQT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.64
• 重原子数：
  44.0
• 可旋转键数：
  5.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  87.23
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  1,7-dipyrrolidinyl-perylene-9,10-(N-butyl)-dicarboxyimide-3,4-dicarboxylic anhydride 、 2,2',7,7′-四氨基-9,9′-联二螺旋芴 在 咪唑 作用下， 以 甲苯 为溶剂， 反应 1.0h， 以6%的产率得到
  参考文献：
  名称：

  Perylenetetracarboxylic Diimide Derivatives Linked with Spirobifluorene

  摘要：

  A series of perylenetetracarboxylic diimide (PDI) compounds linked with spirobifluorene have been prepared. The orthogonal configuration of the PDI subunits efficiently hindered their molecular aggregation in solution. Energy transfer from a 1,7-diphenoxyl group substituted PDI (PO-PDI) to a 1,7-dipyrrolidinyl group substituted PDI (PY-PDI) occurred with a large efficiency when PO-PDI was selectively excited, despite the orthogonal orientation of the two units. This observation was in direct conflict with predictions derived from the Forster theory. More interestingly, this efficient energy transfer also occurred in the solid state.

  DOI：

  10.1021/ol300985h
• 作为产物：
  描述：

  N,N'-dibutyl-1,7-dipyrrolidinyl-3,4,9,10-perylenetetracarboxylic diimide 在 potassium hydroxide 、 溶剂黄146 作用下， 以 异丙醇 为溶剂， 反应 7.0h， 以45%的产率得到1,7-dipyrrolidinyl-perylene-9,10-(N-butyl)-dicarboxyimide-3,4-dicarboxylic anhydride
  参考文献：
  名称：

  Perylenetetracarboxylic Diimide Derivatives Linked with Spirobifluorene

  摘要：

  A series of perylenetetracarboxylic diimide (PDI) compounds linked with spirobifluorene have been prepared. The orthogonal configuration of the PDI subunits efficiently hindered their molecular aggregation in solution. Energy transfer from a 1,7-diphenoxyl group substituted PDI (PO-PDI) to a 1,7-dipyrrolidinyl group substituted PDI (PY-PDI) occurred with a large efficiency when PO-PDI was selectively excited, despite the orthogonal orientation of the two units. This observation was in direct conflict with predictions derived from the Forster theory. More interestingly, this efficient energy transfer also occurred in the solid state.

  DOI：

  10.1021/ol300985h