| 1403560-21-3

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 1403560-21-3
• 化学式: C₃₄H₂₅Br₂N₃S
• 分子量: 667.467
• InChiKey: ACWCQGXNYJLCJP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.74
• 重原子数：
  40.0
• 可旋转键数：
  7.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  50.82
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  对溴苯乙腈 、 10-butyl-10H-phenothiazine-3,7-dicarbaldehyde 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 70.0h， 以73%的产率得到
  参考文献：
  名称：

  Photocatalysis by Phenothiazine Dyes: Visible-Light-Driven Oxidative Coupling of Primary Amines at Ambient Temperature

  摘要：

  New phenothiazine based organic dyes were prepared for visible-light-driven organic transformations. The 3,7-disubstituted phenothiazine derivatives showed visible light absorption and reversible one-electron oxidation behavior. In the presence of 0.5 mol % of 3,7-disubstituted phenothiazines, primary benzylamines showed oxidative coupling under visible light irradiation from a blue LED. The electronic effect of substituents in phenothiazine dyes was observed in catalytic activities. The mechanistic pathway of oxidative coupling was discussed based on the detection of H2O2 after the reaction.

  DOI：

  10.1021/ol302584y