4,6-(MeO)2-2-HOC6H3CHNCH2CH2CH2NCHC6H3-2-OH-4,6-(OMe)2 | 188482-92-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4,6-(MeO)2-2-HOC6H3CHNCH2CH2CH2NCHC6H3-2-OH-4,6-(OMe)2
• 英文别名: 2-[3-[(2-Hydroxy-4,6-dimethoxyphenyl)methylideneamino]propyliminomethyl]-3,5-dimethoxyphenol
• CAS: 188482-92-0
• 化学式: C₂₁H₂₆N₂O₆
• 分子量: 402.447
• InChiKey: IOLCDEXVOZPFEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  29
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  102
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  bis(acetylacetonate)oxovanadium 、 4,6-(MeO)2-2-HOC6H3CHNCH2CH2CH2NCHC6H3-2-OH-4,6-(OMe)2 以 not given 为溶剂， 以82%的产率得到oxovanadium(IV) 2,2'-((propane-1,3-diylbis(azaneylylidene))bis(methaneylylidene))bis(3,5-dimethoxyphenolate)
  参考文献：
  名称：

  新的四齿席夫碱，它们的氧钒（IV）配合物以及双齿席夫碱与钒（III）的某些配合物

  摘要：

  摘要描述了在两个亚氨基氮原子之间包含一个，两个或三个碳原子的四齿席夫碱双阴离子新的钒（IV）配合物。这些化合物是单核的或高分子的，如v（V = O）的值所示，具体取决于席夫碱的二价阴离子。没有证据表明电子会沿着聚合物链发生离域化。还分离了一些双齿席夫碱单阴离子钒（III）配合物。报道了[VO（2-OC6H4CHNH）2]的晶体结构和[V（Prhap）3]·甲苯[HPrhap = 2-HOC6H4C（Me）NCH2CH2Me]的结构的初步数据。

  DOI：

  10.1016/s0277-5387(96)00436-6

文献信息

• Synthesis and structural characterisation of new manganese(II) and (III) complexes. Study of their photolytic and catalase activity and X-ray crystal structure of [Mn(3-OMe, 5-Br-salpn)(EtOH)(H2O)]ClO4
  作者：M Maneiro、M.R Bermejo、A Sousa、M Fondo、A.M González、A Sousa-Pedrares、Charles A McAuliffe

  DOI：10.1016/s0277-5387(99)00321-6

  日期：2000.1

  New [(MnL)-L-II(H2O)(2)] and [(MnL)-L-III(H2O)(2)]ClO4 complexes, where L are substituted N,N'-bis(salicylidene)propane-1,3-diamine (H(2)salpn) ligands have been prepared and thoroughly characterised by elemental analysis, IR and mass spectroscopy, conductivity and magnetic measurements at room temperature (and, in the case of 1, at variable temperature). Cyclic and normal pulse voltammetry measurements were also performed. All these studies support an octahedral geometry around the metal with the Schiff base in the equatorial plane acting as tetradentate and solvent molecules in the axial positions. Crystallographic characterisation of 6 confirms this geometry and shows a supramolecular structure involving pi-pi stacking and hydrogen bonding interactions. The ability to split water by these complexes and their catalase activity has also been studied. (C) 2000 Elsevier Science Ltd All rights reserved.