[Zn(4-hydroxybenzenethiolate)2(tetramethylethylenediamine)] | 254734-94-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: [Zn(4-hydroxybenzenethiolate)2(tetramethylethylenediamine)]
• 英文别名: zinc;4-hydroxybenzenethiolate;N,N,N',N'-tetramethylethane-1,2-diamine
• CAS: 254734-94-6
• 化学式: C₁₈H₂₆N₂O₂S₂Zn
• 分子量: 431.939
• InChiKey: LJKSDVRWQRGYJM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四甲基乙二胺 、 4-羟基苯硫酚 、 zinc(II) chloride 在 Na 作用下， 以 乙腈 为溶剂， 以91.8%的产率得到[Zn(4-hydroxybenzenethiolate)2(tetramethylethylenediamine)]
  参考文献：
  名称：

  Chemistry of functionalized thiolates: syntheses and structures of neutral, monomeric [Zn(SC6H4X-4)2(NN)], where X=H, NH2 and OH, and (NN)=nitrogen bases 2,2′-bpy, phen and tmen

  摘要：

  Six neutral monomers of the type [Zn(SC6H4X-4)(2)(N-N)] (where X = H, NH2, OH; (N-N) = tetramethylethylenediamine (tmen); 2,2'-bipyridyl (bpy) and 1,10-phenanthroline (phen)) have been synthesized in quantitative yield by reacting bis(4-substituted benzenethiolato)zinc(II) with an equimolar amount of the dinitrogen bases. The crystal and molecular structures of all the compounds were determined by X-ray crystallography. A simple neutral compound [Zn(SPh)(2)(bpy)] was also prepared for comparison. The compounds show some interesting X-H ... S (where X=O or N) hydrogen bonding pattern in the solid state. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00267-4