Co[Et2NC(S)NP(O)(OPri)2]2 | 919509-70-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Co[Et2NC(S)NP(O)(OPri)2]2
• CAS: 919509-70-9
• 化学式: C₂₂H₄₈CoN₄O₆P₂S₂
• 分子量: 649.719
• InChiKey: HNZPRMGCNVZLKX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-(diisopropoxyphosphoryl)-N',N'-diethyl-thiocarbamide 、 cobalt(II) nitrate hexahydrate 在 KOH 作用下， 以 乙醇 、 水 为溶剂， 以80%的产率得到Co[Et2NC(S)NP(O)(OPri)2]2
  参考文献：
  名称：

  Studies on cobalt(II) complexes with N-thioacylamido(thio)phosphates: X-ray crystal structure of the Co[PhC(S)NP(S)(OPri)2]2

  摘要：

  Reaction of the potassium salts of N-thioacylamidophosphates RC(S)NHP(O)(OPri)(2) (R = Ph, PhNH, p-MeOPhNH, p-BrPhNH, iPrNH, tBuNH, Et2N, c-C5H10N, c-OC4H8N, C-C5HIINH) with Co(II) cation in aqueous EtOH leads to the complexes of Co(L-S)(2) type structure. Complexes Co(B)L-2 were obtained by the reaction of chelate complexes CoL2 (R = Ph, PhNH) with 2,2'-bipyridine and 1,10-phenanthroline. Structures of the compounds obtained were investigated by EIMS, IR, UV-Vis spectroscopy and microanalysis. Complex Co[PhC(S)NP(S)(OPri)](2) was investigated by single crystal X-ray diffraction. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.06.005