9-phenyl[7]helicene | 1444418-40-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 9-phenyl[7]helicene
• 英文别名: 16-Phenylheptacyclo[16.12.0.02,15.03,12.04,9.021,30.024,29]triaconta-1,3(12),4,6,8,10,13,15,17,19,21(30),22,24,26,28-pentadecaene；16-phenylheptacyclo[16.12.0.02,15.03,12.04,9.021,30.024,29]triaconta-1,3(12),4,6,8,10,13,15,17,19,21(30),22,24,26,28-pentadecaene
• CAS: 1444418-40-9
• 化学式: C₃₆H₂₂
• 分子量: 454.571
• InChiKey: UNWJTTYNORMHNN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11
• 重原子数：
  36
• 可旋转键数：
  1
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  9-Bromo<7>helicene 、 苯硼酸 在 potassium phosphate 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 2-二环己基磷-2,4,6-三异丙基联苯 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以80%的产率得到9-phenyl[7]helicene
  参考文献：
  名称：

  Exploration of 9-bromo[7]helicene reactivity

  摘要：

  Exploration of 9-bromo[7]helicene reactivity mainly in Pd-catalyzed reactions is reported. Palladium catalyzed carbon-carbon and carbon-heteroatom coupling reactions provide a large portfolio of racemic helicenes bearing different functional groups in good to excellent yields. Many of the reactions were performed in the microwave reactor keeping reaction time to a minimum compared with conventional synthetic methods. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.05.039

文献信息

• Exploration of 9-bromo[7]helicene reactivity
  作者：Jaroslav Žádný、Petr Velíšek、Martin Jakubec、Jan Sýkora、Vladimír Církva、Jan Storch

  DOI：10.1016/j.tet.2013.05.039

  日期：2013.7

  Exploration of 9-bromo[7]helicene reactivity mainly in Pd-catalyzed reactions is reported. Palladium catalyzed carbon-carbon and carbon-heteroatom coupling reactions provide a large portfolio of racemic helicenes bearing different functional groups in good to excellent yields. Many of the reactions were performed in the microwave reactor keeping reaction time to a minimum compared with conventional synthetic methods. (C) 2013 Elsevier Ltd. All rights reserved.