methyl 3-[(2R)-1-methoxy-1-oxopropan-2-yl]oxynaphthalene-2-carboxylate | 1312028-06-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: methyl 3-[(2R)-1-methoxy-1-oxopropan-2-yl]oxynaphthalene-2-carboxylate
• CAS: 1312028-06-0
• 化学式: C₁₆H₁₆O₅
• 分子量: 288.3
• InChiKey: VPXRCVWUEFFJHS-SNVBAGLBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  methyl 3-[(2R)-1-methoxy-1-oxopropan-2-yl]oxynaphthalene-2-carboxylate 以 环己烷 为溶剂， 生成 、
  参考文献：
  名称：

  Stereoselective photodimerization of alkyl 3-alkoxyl-2-naphthoates

  摘要：

  Photodimerization of methyl 3-alkoxyl-2-naphthoates with chiral auxiliaries in the alkoxyl groups (la and 1b) in organic solutions results in cubane-like photodimers. Asymmetric induction up to 90% diastereomeric excess (de) has been achieved and the absolute configuration of the pair of the diastereomers has been established. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.03.103
• 作为产物：
  描述：

  3-羟基-2-萘甲酸甲酯 、 L-乳酸甲酯 在 偶氮二甲酸二异丙酯 、 三苯基膦 作用下， 以 四氢呋喃 为溶剂， 反应 6.0h， 以70%的产率得到methyl 3-[(2R)-1-methoxy-1-oxopropan-2-yl]oxynaphthalene-2-carboxylate
  参考文献：
  名称：

  Stereoselective photodimerization of alkyl 3-alkoxyl-2-naphthoates

  摘要：

  Photodimerization of methyl 3-alkoxyl-2-naphthoates with chiral auxiliaries in the alkoxyl groups (la and 1b) in organic solutions results in cubane-like photodimers. Asymmetric induction up to 90% diastereomeric excess (de) has been achieved and the absolute configuration of the pair of the diastereomers has been established. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.03.103

文献信息

• Stereoselective photodimerization of alkyl 3-alkoxyl-2-naphthoates
  作者：Hong-Xia Xu、Bin Chen、Li-Ping Zhang、Li-Zhu Wu、Chen-Ho Tung

  DOI：10.1016/j.tetlet.2011.03.103

  日期：2011.6

  Photodimerization of methyl 3-alkoxyl-2-naphthoates with chiral auxiliaries in the alkoxyl groups (la and 1b) in organic solutions results in cubane-like photodimers. Asymmetric induction up to 90% diastereomeric excess (de) has been achieved and the absolute configuration of the pair of the diastereomers has been established. (C) 2011 Elsevier Ltd. All rights reserved.