Acetic acid (1S,4S)-4-bromo-1-((1S,4S,5S,6R,9S)-9-bromo-6-methyl-11-oxa-tricyclo[4.3.2.0^1,5]undec-4-ylmethyl)-3,3-dimethyl-cyclohexyl ester | 83543-88-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: Acetic acid (1S,4S)-4-bromo-1-((1S,4S,5S,6R,9S)-9-bromo-6-methyl-11-oxa-tricyclo[4.3.2.0^1,5]undec-4-ylmethyl)-3,3-dimethyl-cyclohexyl ester
• CAS: 83543-88-8
• 化学式: C₂₂H₃₄Br₂O₃
• 分子量: 506.318
• InChiKey: OZSWKNBOITZDEX-SECQQYICSA-N

反应信息

• 作为产物：
  描述：

  pinnaterpene A 在 lead(IV) acetate 、 碘 作用下， 以 苯 为溶剂， 反应 48.0h， 以67%的产率得到Acetic acid (1S,4S)-4-bromo-1-((1S,4S,5S,6R,9S)-9-bromo-6-methyl-11-oxa-tricyclo[4.3.2.0^1,5]undec-4-ylmethyl)-3,3-dimethyl-cyclohexyl ester
  参考文献：
  名称：

  PINNATERPENES A, B, AND C, NEW DIBROMODITERPENES FROM THE RED ALGALAURENCIA PINNATAYAMADA

  摘要：

  The structures of three dibromoditerpenes, isolated from the title alga and designated as pinnaterpenes A, B, and C, were determined on the basis of the X-ray crystallography as well as the chemical and spectral data.

  DOI：

  10.1246/cl.1982.1389