trans-dichlorobis(theophylline-7-acetic acid)palladium(II) | 162441-01-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并嘧啶类
• 英文名称: trans-dichlorobis(theophylline-7-acetic acid)palladium(II)
• CAS: 162441-01-2
• 化学式: C₁₈H₂₀Cl₂N₈O₈Pd
• 分子量: 653.732
• InChiKey: KBXIEDPYDRBMTC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  茶碱乙酸 、 palladium dichloride 在 potassium chloride 作用下， 以 盐酸 为溶剂， 以80%的产率得到trans-dichlorobis(theophylline-7-acetic acid)palladium(II)
  参考文献：
  名称：

  Complexes of palladium(II) with theophylline-7-acetic acid

  摘要：

  DOI：

  10.1016/s0020-1693(00)84823-9

文献信息

• Metal complexes of theophylline-7-acetic acid. Crystal structure of a nickel(II) compound containing non-coordinated theophylline-7-acetate ion
  作者：Juan M. Salas、Miguel Quirós、M.Angustias Romero、M.Purificación Sánchez、Miguel A. Salas、Rosario Vilaplana

  DOI：10.1016/0277-5387(94)00279-n

  日期：1995.3

  The solids obtained by interaction of theophylline-7-acetic acid with the metal ions nickel(II), cobalt(II) and palladium(II) have been studied by standard thermal and spectroscopic methods. The Structure of the compound formed with nickel(II), hexaaqua nickel(II) theophylline-7-acetate tetrahydrate, has been solved by X-ray diffraction, this being the first example of a metal salt of an anionic purine derivative in which there is not a direct metal-purine bond. Powder X-ray diffraction demonstrates that the cobalt compound is isostructural to the nickel one. A trans-square planar structure with the ligand bound to the palladium via N(9) is proposed for the palladium compound [PdCl2(theophylline-7-acetic acid)(2)].