8-N,8-N,32-N,32-N-tetrabutyl-5,35-dioxa-2,20-diazanonacyclo[19.15.0.03,19.04,12.06,11.013,18.022,27.028,36.029,34]hexatriaconta-1,3(19),4(12),6(11),7,9,13,15,17,20,22,24,26,28(36),29(34),30,32-heptadecaene-8,32-diamine | 946160-12-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 8-N,8-N,32-N,32-N-tetrabutyl-5,35-dioxa-2,20-diazanonacyclo[19.15.0.03,19.04,12.06,11.013,18.022,27.028,36.029,34]hexatriaconta-1,3(19),4(12),6(11),7,9,13,15,17,20,22,24,26,28(36),29(34),30,32-heptadecaene-8,32-diamine
• CAS: 946160-12-9
• 化学式: C₄₈H₅₀N₄O₂
• 分子量: 714.951
• InChiKey: UGHYVKCKQNKYHA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12
• 重原子数：
  54
• 可旋转键数：
  14
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  58.5
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  9-dibutylamino-benzo[b]naphtho[1,2-d]furan-5,6-dione 在 ammonium acetate 、 溶剂黄146 作用下， 反应 3.0h， 以18%的产率得到8-N,8-N,26-N,26-N-tetrabutyl-5,23-dioxa-2,20-diazanonacyclo[19.15.0.03,19.04,12.06,11.013,18.022,30.024,29.031,36]hexatriaconta-1(21),2,4(12),6(11),7,9,13,15,17,19,22(30),24(29),25,27,31,33,35-heptadecaene-8,26-diamine
  参考文献：
  名称：

  Photophysical properties and photostability of novel symmetric polycyclicphenazine-type fluorescent dyes and the dye-doped films

  摘要：

  Novel symmetric polycyclicphenazine-type fluorescent dyes have been synthesized and characterized in solution and in polymer films. The dyes exhibited two strong absorption bands at around 365-428 nm and 519-567 nm and an intense fluorescence band at around 560-600 nm (Phi = 0.70-0.87) in 1,4-dioxane. The dye-doped polymer films showed excellent wavelength conversion function that efficiently convert ultraviolet and yellow lights into red light (Phi = 0.61-0.92). Moreover, the photostability of the dye-doped PS, PMMA, and PLA films has been investigated. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.11.010