1-(9H-fluoren-9-ylmethoxy)-N-[2-[3-[2-[3-[2-[3-[2-[[9H-fluoren-9-ylmethoxy(hydroxy)methylidene]amino]ethoxy]-3-oxopropyl]sulfanylacetyl]oxy-2,2-bis[[2-[3-[2-[[9H-fluoren-9-ylmethoxy(hydroxy)methylidene]amino]ethoxy]-3-oxopropyl]sulfanylacetyl]oxymethyl]propoxy]-2-oxoethyl]sulfanylpropanoyloxy]ethyl]methanimidic acid | 877614-05-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 1-(9H-fluoren-9-ylmethoxy)-N-[2-[3-[2-[3-[2-[3-[2-[[9H-fluoren-9-ylmethoxy(hydroxy)methylidene]amino]ethoxy]-3-oxopropyl]sulfanylacetyl]oxy-2,2-bis[[2-[3-[2-[[9H-fluoren-9-ylmethoxy(hydroxy)methylidene]amino]ethoxy]-3-oxopropyl]sulfanylacetyl]oxymethyl]propoxy]-2-oxoethyl]sulfanylpropanoyloxy]ethyl]methanimidic acid
• CAS: 877614-05-6
• 化学式: C₉₃H₉₆N₄O₂₄S₄
• 分子量: 1782.06
• InChiKey: UPOMAVZLOCZRQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.2
• 重原子数：
  125
• 可旋转键数：
  60
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  465
• 氢给体数：
  4
• 氢受体数：
  28

反应信息

• 作为产物：
  描述：

  2-(9H-fluoren-9-ylmethoxycarbonylamino)ethyl prop-2-enoate 、 季戊四醇四巯基乙酸酯 在 三正丁胺 作用下， 以 二氯甲烷 为溶剂， 反应 72.0h， 以72%的产率得到1-(9H-fluoren-9-ylmethoxy)-N-[2-[3-[2-[3-[2-[3-[2-[[9H-fluoren-9-ylmethoxy(hydroxy)methylidene]amino]ethoxy]-3-oxopropyl]sulfanylacetyl]oxy-2,2-bis[[2-[3-[2-[[9H-fluoren-9-ylmethoxy(hydroxy)methylidene]amino]ethoxy]-3-oxopropyl]sulfanylacetyl]oxymethyl]propoxy]-2-oxoethyl]sulfanylpropanoyloxy]ethyl]methanimidic acid
  参考文献：
  名称：

  Base Multiplying Agents and Base-Reactive Curable Compositions

  摘要：

  为了提供这样一种基数倍增剂，它能够用于交联反应，例如环氧化合物等，通过碱的作用产生另一种基数，并能够高效地进行基数倍增反应，以及使用该基数倍增剂的基反应固化组合物。该发明的基数生成剂由以下式（1）表示：（在式（1）中，X代表氢原子、取代烷基或未取代烷基；Y代表取代或未取代亚烷链；n代表1至4的整数。）

  公开号：

  US20080200580A1

文献信息

• PHOTOCURABLE COMPOSITION
  申请人：Fukui Hiroji

  公开号：US20110097669A1

  公开（公告）日：2011-04-28

  The present invention provides a photocurable composition which contains a photobase generator capable of generating a satisfactory amount of a base in a high quantum yield when irradiated even with a small quantity of light for a short time, and contains a curable compound that is rapidly cured by the generated base such that the composition is cured into a cured product. The photocurable composition comprises: a photobase generator (A) which is a salt of a carboxylic acid (a1-1) represented by the following formula (1-1) with a basic compound (a2), and a curable compound (B) which has, in one molecule thereof, at least two functional groups selected from among epoxy group, (meth)acryloyl group, isocyanato group, acid anhydride group, and alkoxysilyl group, where R1 to R7 in the above formula (1-1) each are hydrogen or an organic group, R1 to R7 may be the same or different, and two of R1 to R7 may be bonded to each other to form a ring structure.

  本发明提供了一种光固化组合物，其包含一种光碱发生剂，当短时间内用少量光照射时，能够生成足量碱，并且具有高量子产率，同时含有一种可固化化合物，该化合物能够被生成的碱迅速固化，从而使组合物固化成为固化产物。该光固化组合物包括：光碱发生剂（A），其是由下式（1-1）所表示的羧酸盐（a1-1）与碱性化合物（a2）形成的，以及一种可固化化合物（B），该化合物在一个分子中具有至少两种官能团，所述官能团选自环氧基团、（甲基）丙烯酰基团、异氰酸酯基团、酸酐基团和烷氧基硅基团，其中上述式（1-1）中的R1至R7分别为氢或有机基团，R1至R7可以相同或不同，其中两个R1至R7可以相互连接形成环结构。
• PHOTOCURABLE PRESSURE-SENSITIVE ADHESIVE COMPOSITION
  申请人：Fukui Hiroji

  公开号：US20100184880A1

  公开（公告）日：2010-07-22

  The present invention provides a photocurable pressure-sensitive adhesive composition which has sufficient adhesion before being irradiated with light, and after being irradiated with light, keeps a sufficient pot life and has a short cure-completion time at a room temperature. A cured product produced from the composition has high adhesion force to adherends difficult to be attached, and excellent durability. The photocurable pressure-sensitive adhesive composition comprises a crosslinking compound (A) that is crosslinkable by the action of a base, a photobase generator (B) which becomes active upon light irradiation to generate a base, and a tackifying component (C).
• PHOTORESPONSIVE GAS-GENERATING MATERIAL, MICROPUMP AND MICROFLUID DEVICE
  申请人：Fukuoka Masateru

  公开号：US20110014096A1

  公开（公告）日：2011-01-20

  The present invention provides a photoresponsive gas-generating material that is to be used in a micropump of a microfluid device having fine channels formed therein, and is capable of effectively generating gases for transporting a microfluid in response to light irradiation and transporting the microfluid at an improved transport efficiency. The present invention also provides a micropump incorporating the photoresponsive gas-generating material. A photoresponsive gas-generating material 13 is to be used in a micropump having fine channels formed in a substrate, and comprises a photo-sensitive acid-generating agent and an acid-sensitive gas-generating agent, and a micropump 10 has the photoresponsive gas-generating material 13 housed therein.
• US7714162B2
  申请人：——

  公开号：US7714162B2

  公开（公告）日：2010-05-11
• US8217096B2
  申请人：——

  公开号：US8217096B2

  公开（公告）日：2012-07-10