5-sulfhydryl-1,10-phenanthroline | 194923-20-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 5-sulfhydryl-1,10-phenanthroline
• 英文别名: 1,10-Phenanthroline-5-thiol
• CAS: 194923-20-1
• 化学式: C₁₂H₈N₂S
• 分子量: 212.275
• InChiKey: KUPCPMLLHMMZFM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  5-sulfhydryl-1,10-phenanthroline 在 硫化氢 、 hydroxide 、 氧气 、 氢气 、 silver nitrate 作用下， 生成 2,9-di-n-butyl-1,10-phenanthroline-5-sulfonic acid
  参考文献：
  名称：

  Preparation of Novel, Functionalized 1,10-Phenanthrolines

  摘要：

  The preparation of hydrophilic 2,9-diatkyl-1,10-phenanthrolines, including phenanthroline-5-sulfonic acids and phenanthrolines with side chain functionality is described. Nucleophilic aromatic substitution chemistry is used to obtain regiochemically defined phenanthroline sulfonic acids by much simpler means than have been available in the past.

  DOI：

  10.1080/00397919708005000
• 作为产物：
  描述：

  5-氯-1,10-菲咯啉 在 乙硫醇钠 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以74%的产率得到5-sulfhydryl-1,10-phenanthroline
  参考文献：
  名称：

  Preparation of Novel, Functionalized 1,10-Phenanthrolines

  摘要：

  The preparation of hydrophilic 2,9-diatkyl-1,10-phenanthrolines, including phenanthroline-5-sulfonic acids and phenanthrolines with side chain functionality is described. Nucleophilic aromatic substitution chemistry is used to obtain regiochemically defined phenanthroline sulfonic acids by much simpler means than have been available in the past.

  DOI：

  10.1080/00397919708005000

文献信息

• DIAMINE COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：EP3561894A1

  公开（公告）日：2019-10-30

  Provided are a diamine compound including a naphthyl-phenyl linker and a 2-carbazolyl group and an organic light-emitting device including the same. The organic light-emitting device includes: a first electrode; a second electrode; and an organic layer between the first electrode and the second electrode and including an emission layer, wherein the organic layer includes the diamine compound including the naphthyl-phenyl linker and the 2-carbazolyl group.

  本发明提供了一种包括萘基-苯基连接体和 2-咔唑基团的二胺化合物，以及一种包括该二胺化合物的有机发光器件。有机发光器件包括：第一电极；第二电极；以及位于第一电极和第二电极之间并包括发射层的有机层，其中有机层包括二胺化合物，该二胺化合物包括萘基-苯基连接体和 2-咔唑基团。
• Aromatic amino siloxane functionalized materials for use in capping porous dielectrics
  申请人：Merck Patent GmbH

  公开号：US11031237B2

  公开（公告）日：2021-06-08

  The present invention relates to new aromatic-amino functional siloxanes, which are compounds comprising one or two tail groups X2, and a linking group L of structure (2) linking each said tail group to said head group, wherein the head group X has structure (1), containing an optional organic moiety Y, wherein the attachment point of said tail group X2 through said linking group L to the head group X1, may be, at positions a, b, c, d, or e. Another aspect of this invention are compositions containing these novel aromatic amino functional siloxane. A further aspect of this invention are compositions comprised of the above novel aromatic-amino functional siloxanes, and also the composition resulting from the aging of these compositions at room temperature for about 1 day to about 4 weeks. Still further aspects of this invention are processes for forming self-assembled monolayers on a substrate, from the aged composition, and also the processes of coating these aged compositions on patterned porous dielectrics to cap them also the processes of metallization of these capped pattered porous dielectrics.

  本发明涉及新的芳香族-氨基官能团硅氧烷，它是由一个或两个尾基X2和一个结构(2)的连接基团L将每个所述尾基与所述头基连接的化合物，其中头基X具有结构(1)，含有任选的有机分子Y，其中所述尾基X2通过所述连接基团L与头基X1的连接点可以是a、b、c、d或e位。 本发明的另一方面是含有这些新的芳香族氨基官能团硅氧烷的组合物。本发明的另一个方面是由上述新型芳香族氨基官能团硅氧烷组成的组合物，以及这些组合物在室温下老化约 1 天至约 4 周后得到的组合物。本发明更进一步的方面是利用老化的组合物在基底上形成自组装单层的工艺，以及将这些老化的组合物涂覆在图案化多孔电介质上以封盖它们的工艺，还有将这些封盖的图案化多孔电介质金属化的工艺。
• Condensed cyclic compound and organic light-emitting device including the same
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP2894157B1

  公开（公告）日：2018-04-04
• 1-AMINODIBENZOFURAN-BASED COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：EP3502107B1

  公开（公告）日：2022-01-26
• METHOD FOR PURIFYING POLYMER AND POLYMER
  申请人：Sunaga Tadahiro

  公开号：US20120208976A1

  公开（公告）日：2012-08-16

  Disclosed is a method for purifying a polymer in which a solution containing a cyclic olefin polymer having at least a repeating structural unit [A] represented by the general formula (1) and a metal component is brought into contact with an organic compound having a basic functional group and an acidic functional group, and then the resulting solution is brought into contact with a basic adsorbent to remove the metal component contained in the solution.