2-[(2-Chlorophenyl)amino]cyclopentan-1-ol | 1179714-59-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-[(2-Chlorophenyl)amino]cyclopentan-1-ol
• 英文别名: 2-(2-chloroanilino)cyclopentan-1-ol
• CAS: 1179714-59-0
• 化学式: C₁₁H₁₄ClNO
• 分子量: 211.691
• InChiKey: YXXTYANVBPPGJY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  32.3
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,2-环氧环戊烷 、 邻氯苯胺 在 20% cobalt ferrite and reduced graphene oxide nanohybrids 作用下， 以 neat (no solvent) 为溶剂， 反应 0.2h， 以89%的产率得到2-[(2-Chlorophenyl)amino]cyclopentan-1-ol
  参考文献：
  名称：

  Graphene based magnetic nanohybrids as promising catalysts for the green synthesis of β-amino alcohol derivatives

  摘要：

  The principle of green chemistry evolves around designing products and processes with catalyst retrieval as its foremost aim. In this regard, the present report encompasses the synthesis of graphene based magnetic nanohybrids (CoFe@rGO) and their catalytic evaluation for epoxide ring opening reactions. Numerous techniques were employed for sample characterization. Powder X- Ray diffraction patterns confirm the single phase cubic structure corresponding to CoFe2O4 with Fd-3m space group. The average crystallite size was observed to be in the range of 8-12 nm for all the samples which was calculated in accordance with Debye-Scherrer equation. The FE-SEM and HR-TEM techniques were utilized to obtain detailed structural analysis of the nanohybrids displaying layered structure of GO decorated with CoFe2O4 nanoparticles. The EDX spectra confirm the elemental purity of the synthesized materials. Magnetic measurements were investigated by vibrating sample magnetometer, displaying the increase in saturation magnetization values with increase in CoFe2O4 concentration from 32.7 emu/g for CoFe@rGO (5%) to 38.6 emu/g for CoFe@rGO (20%). The catalytic presentation of the synthesized nanohybrids was evaluated for epoxide ring opening reactions under solvent free conditions displaying 100% conversion rates within 6 min of reaction time. (C) 2019 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2019.127522

文献信息

• Lead(II) arenedisulfonate coordination polymer: Synthesis, crystal structure and properties
  作者：Li Wang、GuanFeng Li、Mengjie Liu、Dongsheng Deng、Yamei Pei、Xinyi Wang

  DOI：10.1016/j.inoche.2013.06.006

  日期：2013.9

  A new 1-D coordination polymer, [Pb(Phen)(1,5-nds)(H2O)(2)]H2O) (1), was constructed from 1,5-naphthalenedisulfonate (1,5-nds), 1,10-phenanthroline (Phen) and Pb(CH3COO)(2)center dot 3H(2)O with easily reachable lead sites, which can be subsequently used to promote the epoxide ring-opening reaction of epoxides and amines with remarkable catalytic activity. In addition, the thermal and luminescent properties of 1 in the solid state were also investigated. (C) 2013 Elsevier B.V. All rights reserved.