chromium(III) (acetate)tetraphenylporphyrinate | 82025-66-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: chromium(III) (acetate)tetraphenylporphyrinate
• 英文别名: (acetato)chromium(III)tetraphenylporphine；(Ac)Cr(tetraphenylporphine)；(AcO)CrTPP
• CAS: 82025-66-9
• 化学式: C₄₆H₃₁CrN₄O₂
• 分子量: 723.774
• InChiKey: YLFJDLCKKKHXPC-YKKPBKTHSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  chromium(III) (acetate)tetraphenylporphyrinate 在 吡啶 作用下， 以 氯仿 为溶剂， 生成 bis((acetato)chromium(III)tetraphenylporphine)pyridine
  参考文献：
  名称：

  Golubchikov, O. A.; Tsyganov, D. V.; Semeikin, A. S., Russian Journal of Coordination Chemistry, 1993, vol. 19/9, p. 655 - 659

  摘要：

  DOI：
• 作为产物：
  描述：

  四苯基卟啉 、 chromium(II) acetate hydrate 在 air 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以96%的产率得到chromium(III) (acetate)tetraphenylporphyrinate
  参考文献：
  名称：

  Golubchikov, O. A.; Tsyganov, D. V.; Semeikin, A. S., Russian Journal of Coordination Chemistry, 1993, vol. 19/9, p. 655 - 659

  摘要：

  DOI：

文献信息

• Lomova, T. N.; Berezin, B. D.; Oparin, L. V., Russian Journal of Inorganic Chemistry, 1982, vol. 27, p. 383 - 386
  作者：Lomova, T. N.、Berezin, B. D.、Oparin, L. V.、Zvezdina, V. V.

  DOI：——

  日期：——
• ——
  作者：S. V. Zaitseva、S. A. Zdanovich、O. A. Golubchikov

  DOI：10.1023/a:1021630228084

  日期：——

  Stable chromium complex (AcO)CrTPP was synthesized through the reaction of meso-tetraphenylporphine with chromium(HI) acetate in boiling phenol. Coordination properties of chromium porphyrin in reaction with imidazole and pyridine in o-xylene were studied by electronic absorption spectroscopy and computer modeling. A single-electron oxidation of chromium(III) complex was found to be affected by peroxide compounds. The stability of an extra complex depends on the basic properties of the extra ligand and oxidation number of the central metal atom. The complex stability correlates with the calculated energy of formation of the metal-extra ligand bond. The geometrical structure and energy parameters of hexacoordinated chromium porphyrins were calculated using the quantum-chemical method. The effect of the cis and trans position of ligands in the composition of a macrocyclic compound was established to be significant only in the extra complexes (AcO)CrTPP.
• Tipugina; Lomova, Russian Journal of Inorganic Chemistry, 2002, vol. 47, # 7, p. 978 - 982
  作者：Tipugina、Lomova

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• Tipugina; Lomova, Russian Journal of Physical Chemistry, 2002, vol. 76, # 4, p. 567 - 571
  作者：Tipugina、Lomova

  DOI：——

  日期：——
• Tipugina; Lomova; Ageeva, Russian Journal of General Chemistry, 1999, vol. 69, # 3, p. 441 - 445
  作者：Tipugina、Lomova、Ageeva

  DOI：——

  日期：——