N-(furan-2-ylmethylene)-2-(1-(2-hydroxyphenyl)ethylidene)hydrazine-1-carbothioamide | 1277174-61-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: N-(furan-2-ylmethylene)-2-(1-(2-hydroxyphenyl)ethylidene)hydrazine-1-carbothioamide
• CAS: 1277174-61-4
• 化学式: C₁₄H₁₃N₃O₂S
• 分子量: 287.342
• InChiKey: UBUPJJNICVLGFI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  20.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  70.12
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  糠醛 、 2'-羟基苯乙酮 、 氨基硫脲 在 溶剂黄146 作用下， 以 乙醇 为溶剂， 反应 6.0h， 生成 N-(furan-2-ylmethylene)-2-(1-(2-hydroxyphenyl)ethylidene)hydrazine-1-carbothioamide
  参考文献：
  名称：

  Spectroscopic, catalytic, and biological studies on mononuclear ruthenium(II) ONSN chelating thiosemicarbazone complexes

  摘要：

  A group of new ruthenium(II) thiosemicarbazone complexes, [Ru(CO)(B)(L)] (where B = PPh3/AsPh3/Py; L = dibasic tetradentate Schiff-base ligand), have been synthesized by reacting [RuHCl(CO)(PPh3)(3)], [RuHCl(CO)(AsPh3)(3)], and [RuHCl(CO)(Py)(PPh3)(2)] with the Schiff base in 1:1 molar ratio in an ethanol-benzene mixture. These complexes have been characterized by elemental analysis, FT-IR, UV-Vis, NMR, and mass spectroscopy. The redox behaviors of the complexes have been investigated by cyclic voltammetry. These complexes have been examined for their catalytic efficiency for aryl-aryl coupling and oxidation of primary and secondary alcohols into their corresponding aldehydes and ketones in the presence of oxygen. All the complexes were screened for their antibacterial activity. Further, one complex was tested for its binding with calf thymus-DNA using absorption spectroscopic studies and viscosity measurements.

  DOI：

  10.1080/00958972.2011.556721