2-(benzo[d]thiazol-2-yl)-5-tert-butyl-phenol | 1422963-58-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: 2-(benzo[d]thiazol-2-yl)-5-tert-butyl-phenol
• 英文别名: 2-(1,3-Benzothiazol-2-yl)-5-tert-butylphenol
• CAS: 1422963-58-3
• 化学式: C₁₇H₁₇NOS
• 分子量: 283.394
• InChiKey: NFRIRRPPTBKBFS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  61.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  溶剂黄146 、 2-[4-(2-甲基-2-丙基)苯基]-1,3-苯并噻唑 在 碘苯二乙酸 、 palladium diacetate 作用下， 反应 5.0h， 以68%的产率得到2-(benzo[d]thiazol-2-yl)-5-tert-butyl-phenol
  参考文献：
  名称：

  通过底物定向的C–H活化，对2-芳基苯并噻唑进行区域选择性的邻羟基化

  摘要：

  一种有效的协议已用于直接被开发邻的羟基化2- arylbenzothiazole使用Pd（OAc）2作为催化剂和任一的DIB / AcOH中或过硫酸氢钾® / TFA在空气气氛下的组合。在这两种条件下，该方法都能耐受各种各样的取代基，从而使相应的邻羟基化产物的收率极佳。在苯环的间位位置具有取代基的苯环的较少空间位阻的位点观察到区域选择性羟基化。

  DOI：

  10.1016/j.tet.2012.12.067

文献信息

• ORGANIC LIGHT-EMITTING ELEMENT AND DISPLAY APPARATUS
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20150333279A1

  公开（公告）日：2015-11-19

  Provided is an organic light-emitting element having high luminous efficiency and a long lifetime. The organic light-emitting element includes a pair of electrodes and an organic compound layer placed between the pair of electrodes, in which the organic compound layer includes an iridium complex having a benzo[f]isoquinoline of a specific structure as a ligand and a metal complex compound of a specific structure.
• ORGANIC LIGHT-EMITTING ELEMENT
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20150357587A1

  公开（公告）日：2015-12-10

  Provided is an organic light-emitting element having high light-emitting efficiency and a long element lifetime. The organic light-emitting element includes an anode, a cathode, and an organic compound layer placed between the anode and the cathode, and the organic compound layer includes an iridium complex represented by the following general formula [1] and a metal complex represented by the following general formula [9]. Ir(L 1 )(L 2 )(L 3 )  [1] MLL′  [9]
• ORGANIC LIGHT-EMITTING DEVICE AND DISPLAY APPARATUS
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20150364703A1

  公开（公告）日：2015-12-17

  Provided is a long-lifetime organic light-emitting element having a good device lifetime characteristic. The organic light-emitting device includes: a pair of electrodes; and an organic compound layer placed between the pair of electrodes, in which the organic compound layer includes an iridium complex having a specific structure and a different kind of metal complex.
• US9466804B2
  申请人：——

  公开号：US9466804B2

  公开（公告）日：2016-10-11
• US9601704B2
  申请人：——

  公开号：US9601704B2

  公开（公告）日：2017-03-21