bis(1-adamantyl acetoacetato)copper(II) | 1242002-99-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis(1-adamantyl acetoacetato)copper(II)
• CAS: 1242002-99-8
• 化学式: C₂₈H₃₈CuO₆
• 分子量: 534.152
• InChiKey: AMLDFONBTXEYLA-XCGPZNIKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper diacetate 、 adamantan-1-yl 3-oxobutanoate 以 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 bis(1-adamantyl acetoacetato)copper(II)
  参考文献：
  名称：

  Crystal structure and spectral characteristics of Bis(1-adamantyl acetoacetato)copper(II)

  摘要：

  The structure of a new complex bis(1-adamantyl acetoacetato)copper(II) was studied by X-ray crystallography, electronic absorption spectroscopy in the visible, and vibrational spectroscopy. Copper atoms have a square coordination in both solutions and crystals. The crystals are triclinic, space group P (1) over bar, a = 6.9389(6) angstrom, b = 9.0697(8) angstrom, c = 11.4280(10) angstrom, alpha = 109.279(4)degrees, beta = 100.179(4)degrees, gamma = 98.171(4)degrees, V = 652.45(10) angstrom(3), Z = 2. Molecules form the crystals only due to van der Waals forces, because Cu-C intermolecular interactions, which are characteristic of other beta-dicarbonyl complexes of copper(II), are absent.

  DOI：

  10.1134/s0036023609120158