N-[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]phenyl]-N-[4-[1-[4-[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]-N-(3,4,5-trifluorophenyl)anilino]phenyl]cyclohexyl]phenyl]-3,4,5-trifluoroaniline | 1422952-06-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]phenyl]-N-[4-[1-[4-[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]-N-(3,4,5-trifluorophenyl)anilino]phenyl]cyclohexyl]phenyl]-3,4,5-trifluoroaniline
• CAS: 1422952-06-4
• 化学式: C₆₆H₇₆F₆N₂O₄
• 分子量: 1075.33
• InChiKey: BNBQQQJJRZHSBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.3
• 重原子数：
  78
• 可旋转键数：
  28
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  1,1-双(4-氨基苯基)环己烷 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 生成 N-[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]phenyl]-N-[4-[1-[4-[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]-N-(3,4,5-trifluorophenyl)anilino]phenyl]cyclohexyl]phenyl]-3,4,5-trifluoroaniline
  参考文献：
  名称：

  Crosslinkable TAPC-Based Hole-Transport Materials for Solution-Processed Organic Light-Emitting Diodes with Reduced Efficiency Roll-Off

  摘要：

  Abstract1‐Bis[4‐[N,N‐di(4‐tolyl)amino]phenyl]‐cyclohexane (TAPC) has been widely used in xerography and organic light‐emitting diodes (OLEDs), but derivatives are little known. Here, a new series of solution‐processable, crosslinkable hole conductors based on TAPC with varying highest occupied molecular orbital (HOMO) energies from −5.23 eV to −5.69 eV is implemented in blue phosphorescent OLEDs. Their superior perfomance compared with the well‐known N4,N4,N4′,N4′‐tetraphenylbiphenyl‐4,4′‐diamine (TPDs) analogues regarding hole‐injection and mobility, electron and exciton blocking capabilities, efficiency, and efficiency roll‐off is demonstrated. Overall, the TAPC‐based devices feature higher luminous and power efficiency over a broader range of brightness levels and reduced efficiency roll off. A systematic broadening of the emission zone is observed as the hole‐injection barrier between the anode and the hole‐transporting layer increased.

  DOI：

  10.1002/adfm.201201197

文献信息

• LIGANDS FOR QUANTUM DOTS IN CROSS-LINKED EMISSIVE LAYER OF QUANTUM DOT LIGHT EMITTING DIODES
  申请人：Sharp Kabushiki Kaisha

  公开号：US20210408416A1

  公开（公告）日：2021-12-30

  A light-emitting device includes an anode, a cathode, and a crosslinked emissive layer disposed between the anode and the cathode in which quantum dots are dispersed. The crosslinked layer includes a crosslinked material and quantum dots dispersed in the crosslinked mater, the quantum dots having ligands respectively bonded to the quantum dots. The quantum dots are distributed unevenly within the crosslinked material. The ligands have a concentration relative to the weight of the quantum dots of 10 to 45 wt %. A method of forming a crosslinked emissive layer of a light-emitting device in which quantum dots are dispersed includes the steps of depositing a mixture on a deposition surface and subjecting at least a portion of the mixture to an activation stimulus to crosslink the cross-linkable material.
• POROUS ELECTRODE AND METHOD FOR ITS PREPARATION
  申请人：Universität zu Köln

  公开号：US20220190339A1

  公开（公告）日：2022-06-16

  The present invention relates to an electrode comprising an organic compound prepared by polymerization of a triaryl amine having at least one reactive polymerizable group, whereby the organic compound has at least a bimodal pore size distribution. Moreover, the present invention relates to a method for the preparation of such an electrode.