N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene | 1161783-13-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene
• 英文别名: N'-hydroxy-2-(hydroxyimino)-N-(4-{[(2-hydroxyphenyl)-methylene]amino}-1-naphthyl)ethanimidamide；N-hydroxy-2-hydroxyimino-N'-[4-[(2-hydroxyphenyl)methylideneamino]naphthalen-1-yl]ethanimidamide
• CAS: 1161783-13-6
• 化学式: C₁₉H₁₆N₄O₃
• 分子量: 348.361
• InChiKey: AAFBWHLNGUSYLO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  110
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  nickel(II) acetate tetrahydrate 、 N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 以77%的产率得到[Ni3(N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene(-2H))2(H2O)4][CH3COO]2
  参考文献：
  名称：

  Synthesis and characteristics of N-(glyoxyldioxime)-N′-(2-hydroxybenzylidene)-1,4-diaminonaphthalene and its metal complexes

  摘要：

  A new vic-dioxime, N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene, was synthesized proceeding from naphthalene. Its complexes of nickel, copper and cobalt were prepared. The vic-dioxime and its complexes were charecterized by FT-IR, UV, H-1 NMR, mass spectrometry, elemental analysis, DTA/TG analysis techniques and conductometric measurements.

  DOI：

  10.1134/s1070363208050186
• 作为产物：
  描述：

  chloroglyoxime 、 2-[(4-aminonaphthalen-1-ylimino)methyl]phenol 在 碳酸氢钠 作用下， 以 乙醇 、 水 为溶剂， 反应 5.0h， 以57%的产率得到N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene
  参考文献：
  名称：

  Synthesis and characteristics of N-(glyoxyldioxime)-N′-(2-hydroxybenzylidene)-1,4-diaminonaphthalene and its metal complexes

  摘要：

  A new vic-dioxime, N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene, was synthesized proceeding from naphthalene. Its complexes of nickel, copper and cobalt were prepared. The vic-dioxime and its complexes were charecterized by FT-IR, UV, H-1 NMR, mass spectrometry, elemental analysis, DTA/TG analysis techniques and conductometric measurements.

  DOI：

  10.1134/s1070363208050186