O=Re(OAc)(5,10,15,20-tetraphenyl-21H,23H-porphinato) | 128873-19-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: O=Re(OAc)(5,10,15,20-tetraphenyl-21H,23H-porphinato)
• 英文别名: OAc-oxo{5,10,15,20-tetraphenylporphyrinato}rhenium(V)}
• CAS: 128873-19-8
• 化学式: C₄₆H₃₁N₄O₃Re
• 分子量: 873.984
• InChiKey: WTZXNDFETDMLFY-NBICUONBSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [O=ReTPP]2O 、 溶剂黄146 以 苯 为溶剂， 生成 O=Re(OAc)(5,10,15,20-tetraphenyl-21H,23H-porphinato)
  参考文献：
  名称：

  The state of 5,10,15,20-tetraphenyl-21H,23H-porphine rhenium(V) complexes in solutions of acids

  摘要：

  The spectral properties (UV/Vis, IR, H-1 NMR) and stability of diverse forms of 5,10,15,20-tetraphenyl-21H,23H-porphine rhenium(V) complexes in neutral and protolytic solvents have been studied. Quantitative characteristics have been obtained for the reactions of formation and interconversion of the mu-oxo dimeric and monomeric rhenium(V) complex species in the benzene-AcOH system and dissociation at the coordination center of the H+-associated form of the monomeric rhenium(V) complex in mixed H2O-H2SO4 solvents in a wide range of component concentrations. It has been shown that the stability of the coordination center of the rhenium(V) complexes sharply depends on the nature of a second acido ligand, in addition to the coordinated porphyrin.

  DOI：

  10.1134/s0036023613110223