Tetrabutyl pyrazino[2,3-g]quinoxaline-2,3,7,8-tetracarboxylate | 1343403-52-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: Tetrabutyl pyrazino[2,3-g]quinoxaline-2,3,7,8-tetracarboxylate
• 英文别名: tetrabutyl pyrazino[2,3-g]quinoxaline-2,3,7,8-tetracarboxylate
• CAS: 1343403-52-0
• 化学式: C₃₀H₃₈N₄O₈
• 分子量: 582.654
• InChiKey: FAXYFAOWHCRLLZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  42
• 可旋转键数：
  20
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  157
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  dibutyl 2,3-dioxosuccinate 、 1,2,4,5-benzenetetraamine tetrahydrochloride 在 sodium acetate 、 溶剂黄146 作用下， 反应 18.0h， 以0.86 g的产率得到Tetrabutyl pyrazino[2,3-g]quinoxaline-2,3,7,8-tetracarboxylate
  参考文献：
  名称：

  Novel, Low-Cost, Highly Soluble n-Type Semiconductors: Tetraazaanthracene Tetraesters

  摘要：

  New tetraester derivatives of 1,4,5,8-tetraazaanthracene have been prepared and characterized by spectroscopic and electrochemical techniques. The LUMO level of the compounds is close to -4 eV (the so-called air operating stability border in n-channel field effect transistors). Tetraesters were obtained with reasonable yields without the necessity of using high-quality reactants or solvents, resulting in their low cost.

  DOI：

  10.1021/ol2025789

文献信息

• [EN] PHOTOACTIVE MATERIAL<br/>[FR] MATÉRIAU PHOTOACTIF
  申请人：[en]SUMITOMO CHEMICAL CO., LTD

  公开号：WO2021156605A1

  公开（公告）日：2021-08-12

  A material comprising an electron-accepting unit of formula (I): wherein Ar1 and Ar2 independently is a 5- or 6-membered aromatic or heteroaromatic ring or is absent; and each X is independently H or a substituent with the proviso that at least one X is an electron-withdrawing group and wherein X groups bound to adjacent carbon atoms may be linked to form an electron-withdrawing group. The material further comprises an electron-donating unit D comprising a fused or unfused furan or thiophene. The material may be a polymer comprising repeat units of formula (I). The material may be a non- polymeric compound. An organic photodetector may contain a bulk heterojunction layer containing an electron acceptor or an electron donor wherein at least one of the electron acceptor and electron donor contains a unit of formula (I).
• TW2021/38374
  申请人：——

  公开号：——

  公开（公告）日：——
• Novel, Low-Cost, Highly Soluble n-Type Semiconductors: Tetraazaanthracene Tetraesters
  作者：P. Gawrys、T. Marszalek、E. Bartnik、M. Kucinska、J. Ulanski、M. Zagorska

  DOI：10.1021/ol2025789

  日期：2011.11.18

  New tetraester derivatives of 1,4,5,8-tetraazaanthracene have been prepared and characterized by spectroscopic and electrochemical techniques. The LUMO level of the compounds is close to -4 eV (the so-called air operating stability border in n-channel field effect transistors). Tetraesters were obtained with reasonable yields without the necessity of using high-quality reactants or solvents, resulting in their low cost.