2,4,6-Tris[7-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl]-1,3,5-triazine | 1191456-79-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 2,4,6-Tris[7-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl]-1,3,5-triazine
• 英文别名: 2,4,6-tris[7-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl]-1,3,5-triazine
• CAS: 1191456-79-7
• 化学式: C₃₉H₂₇N₃O₁₂S₆
• 分子量: 922.052
• InChiKey: NUKGCBWVTWVJLB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  60
• 可旋转键数：
  6
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  319
• 氢给体数：
  0
• 氢受体数：
  21

反应信息

• 作为产物：
  描述：

  三聚氯氰 、 5-(tributyltin)-2,2′-bis(3,4-ethylenedioxy)thiophene 在 四(三苯基膦)钯 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以30%的产率得到2,4,6-Tris[7-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl]-1,3,5-triazine
  参考文献：
  名称：

  Star-shaped triazine–thiophene conjugated systems

  摘要：

  Star-shaped molecules consisting of short-chain oligothiophenes attached onto an electron acceptor triazine core have been synthesized. Results of the analysis of the electronic properties of these compounds by UV-vis spectroscopy and cyclic voltammetry are used to discuss the impact of the electron-withdrawing node on the properties of the compounds. The electrochemical oxidation of some of these systems into the corresponding electroactive polymers is briefly discussed. (C) 2009 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2009.07.126