2,7,13,18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.3.1.1]-tetracosa-1(23),8(24),9,11,19,21-hexane-9,11,20,22-tetraol | 1178976-24-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2,7,13,18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.3.1.1]-tetracosa-1(23),8(24),9,11,19,21-hexane-9,11,20,22-tetraol
• 英文别名: 2,7,13,18-Tetramethyl-3,6,14,17-tetrazatricyclo[17.3.1.18,12]tetracosa-1(23),8(24),9,11,19,21-hexaene-9,11,20,22-tetrol；2,7,13,18-tetramethyl-3,6,14,17-tetrazatricyclo[17.3.1.18,12]tetracosa-1(23),8(24),9,11,19,21-hexaene-9,11,20,22-tetrol
• CAS: 1178976-24-3
• 化学式: C₂₄H₃₆N₄O₄
• 分子量: 444.574
• InChiKey: SAHWGXMGAFZFRE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  32
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  129
• 氢给体数：
  8
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  2,7,13,18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.3.1.1]-tetracosa-1(23),8(24),9,11,19,21-hexane-9,11,20,22-tetraol 、 copper(II) acetate monohydrate 以 乙醇 为溶剂， 生成 [Cu2(2,7,13,18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.3.1.1]-tetracosa-1(23),8(24),9,11,19,21-hexane-9,11,20,22-tetraol(4-))]
  参考文献：
  名称：

  Synthesis, characterization and catalytic oxidation of cyclohexane using a novel host (zeolite-Y)/guest (binuclear transition metal complexes) nanocomposite materials

  摘要：

  Transition metal (M = Mn(II), Co(II), Ni(II) and Cu(II)) complexes with octahydro-Schiff base (H-4-N4O4) = 2,7,13,18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.3.1.1]-tetracosa-1(23), 2,6,8(24), 9,11,13,17,19,21-decaene-9,11,20,22-tetraol; H-4([H](8)-N4O4) = 2,7,13,, 18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.13.1. 1.]-tetracosa-1(23), 8(24), 9,11,19,21-hexane-9,11,20,22-tetraol) have been encapsulated in nanopores of zeolite-Y; [M([H](8)-N4O4)]@NaY; with Flexible Ligand Method (FLM) for the first time. The new Host-Guest Nanocomposite Materials (HGNM) was characterized by several techniques: chemical analysis, spectroscopic methods (DRS, FT-IR and UV/Vis), BET technique, conductometric and magnetic measurements. The catalytic activities for oxidation of cyclohexane with HGNM complexes are reported. Zeolite encapsulated octahydro-Schiff base copper(II) complex; [Cu([H](8)-N4O4)]@NaY; was found to be more active than the corresponding cobalt(II), manganese(II) and nickel(II) complexes for cyclohexane oxidation. The catalytic properties of the complexes are influenced by their geometry and by the steric environment of the active sites. HGNM are stable enough to be reused and are suitable to be utilized as partial oxidation catalysts. The encapsulated catalysts systems; [M([H](8)-N4O4)]@NaY; were more active than the corresponding neat complexes; [M([H](8)-N4O4)))]. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.04.028

文献信息

• Synthesis, characterization and catalytic oxidation of cyclohexane using a novel host (zeolite-Y)/guest (binuclear transition metal complexes) nanocomposite materials
  作者：Masoud Salavati-Niasari、Zohreh Salimi、Mahdi Bazarganipour、Fatemeh Davar

  DOI：10.1016/j.ica.2009.04.028

  日期：2009.8

  Transition metal (M = Mn(II), Co(II), Ni(II) and Cu(II)) complexes with octahydro-Schiff base (H-4-N4O4) = 2,7,13,18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.3.1.1]-tetracosa-1(23), 2,6,8(24), 9,11,13,17,19,21-decaene-9,11,20,22-tetraol; H-4([H](8)-N4O4) = 2,7,13,, 18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.13.1. 1.]-tetracosa-1(23), 8(24), 9,11,19,21-hexane-9,11,20,22-tetraol) have been encapsulated in nanopores of zeolite-Y; [M([H](8)-N4O4)]@NaY; with Flexible Ligand Method (FLM) for the first time. The new Host-Guest Nanocomposite Materials (HGNM) was characterized by several techniques: chemical analysis, spectroscopic methods (DRS, FT-IR and UV/Vis), BET technique, conductometric and magnetic measurements. The catalytic activities for oxidation of cyclohexane with HGNM complexes are reported. Zeolite encapsulated octahydro-Schiff base copper(II) complex; [Cu([H](8)-N4O4)]@NaY; was found to be more active than the corresponding cobalt(II), manganese(II) and nickel(II) complexes for cyclohexane oxidation. The catalytic properties of the complexes are influenced by their geometry and by the steric environment of the active sites. HGNM are stable enough to be reused and are suitable to be utilized as partial oxidation catalysts. The encapsulated catalysts systems; [M([H](8)-N4O4)]@NaY; were more active than the corresponding neat complexes; [M([H](8)-N4O4)))]. (C) 2009 Elsevier B. V. All rights reserved.