o,o'-Diazidoazobenzol | 3364-08-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: o,o'-Diazidoazobenzol
• 英文别名: 2,2'-Diazidoazobenzene；[[6-[(6-diazonioiminocyclohexa-2,4-dien-1-ylidene)hydrazinylidene]cyclohexa-2,4-dien-1-ylidene]hydrazinylidene]azanide
• CAS: 3364-08-7
• 化学式: C₁₂H₈N₈
• 分子量: 264.249
• InChiKey: GHVZQKAJOLRKIE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  91
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  o,o'-Diazidoazobenzol 以 gaseous matrix 为溶剂， 生成 二苯并-1,3a,4,6a-四氮杂并环戊二烯
  参考文献：
  名称：

  Intermediates in photolyses of 2,2′-diazidoazobenzene and 2-azidoazobenzene in low-temperature matrices

  摘要：

  The photolyses of 2,2'-diazidoazobenzene (1) and 2-azidoazobenzene (4) were investigated in argon and 2-methyltetrahydrofuran (MTHF) matrices at cryogenic temperature. Nitrene and dinitrene were observed in the photolysis of 1 in an MTHF matrix by electron spin resonance (ESR). The dinitrene in an argon matrix was also observed by ultraviolet-visible (UV-vis) and Fourier transform infrared (FT-IR) spectroscopies. UV absorption bands at 430 and 460 nm and IR peak at 1263 cm(-1) were assigned to the dinitrene. Furthermore, mononitrene as an intermediate of the photolysis of 4 was confirmed by UV-vis and FT-IR spectroscopies in an argon matrix. An IR band at 1225 cm(-1) of mononitrene was observed. (C) 1998 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(97)00231-x

文献信息

• Intermediates in photolyses of 2,2′-diazidoazobenzene and 2-azidoazobenzene in low-temperature matrices
  作者：Tsuguyori Ohana、Yoshinori Koga

  DOI：10.1016/s1386-1425(97)00231-x

  日期：1998.3

  The photolyses of 2,2'-diazidoazobenzene (1) and 2-azidoazobenzene (4) were investigated in argon and 2-methyltetrahydrofuran (MTHF) matrices at cryogenic temperature. Nitrene and dinitrene were observed in the photolysis of 1 in an MTHF matrix by electron spin resonance (ESR). The dinitrene in an argon matrix was also observed by ultraviolet-visible (UV-vis) and Fourier transform infrared (FT-IR) spectroscopies. UV absorption bands at 430 and 460 nm and IR peak at 1263 cm(-1) were assigned to the dinitrene. Furthermore, mononitrene as an intermediate of the photolysis of 4 was confirmed by UV-vis and FT-IR spectroscopies in an argon matrix. An IR band at 1225 cm(-1) of mononitrene was observed. (C) 1998 Elsevier Science B.V. All rights reserved.