1,1'-{methylenebis[(3-methyl-5-cyclohexyl-1,4-phenylene)iminomethyl]}bis(2-naphthol) | 1236010-39-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,1'-{methylenebis[(3-methyl-5-cyclohexyl-1,4-phenylene)iminomethyl]}bis(2-naphthol)
• CAS: 1236010-39-1
• 化学式: C₄₉H₅₀N₂O₂
• 分子量: 698.948
• InChiKey: LRGZUBKRPDUDGU-JMTOTSTKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.21
• 重原子数：
  53.0
• 可旋转键数：
  8.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  65.18
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  4,4'-diamino-5,5'dicyclohexyl-3,3'-dimethyldiphenylmethane 、 2-羟基-1-萘甲醛 在 甲酸 作用下， 以 甲醇 为溶剂， 以99%的产率得到1,1'-{methylenebis[(3-methyl-5-cyclohexyl-1,4-phenylene)iminomethyl]}bis(2-naphthol)
  参考文献：
  名称：

  Design of postmetallocene catalytic systems of aryliminetype for olefins polymerization: XIII. Synthesis of tetradentate bis(2-hydroxy-1-naphthaldimine) ligands and their complexes with titanium(IV) dichloride

  摘要：

  Reactions of 2-hydroxy-1-naphthaldehyde with 1,4-diaminobutane, 1,6-diaminohexane, 4,4'-methylenedianiline and its alkyl- and cycloalkyl-sybstituted derivatives, with 4,4'-sulfonyldianiline, 2,2'- and 4,4'-oxydianiline, 4,4'-(1,4-phenylenebisoxy)dianiline, 4,4'-[propane-2,2-diylbis(1,4-phenylenebisoxy)]dianiline, and p-terphenyl-4,4aEuro(3)-diamine afforded a series of the corresponding diimines that at treating with TiCl2(OPr-i)(2) formed mono- and binuclear complexes of titanium(IV) dichloride with tetradentate ligands LTiCl2 and L-2(TiCl2)(2).

  DOI：

  10.1134/s1070428010050246