Polymer emulsion coatings for cellulosic substrates with improved barrier properties
申请人:AIR PRODUCTS POLYMERS, L.P.
公开号:EP1498544A1
公开(公告)日:2005-01-19
A cellulosic product such as paper coating composition is disclosed comprising aqueous-based semi-crystalline vinyl acetate-ethylene polymer emulsions, containing crystalline ethylene segments, which are useful for imparting oil, grease, solvent, water, and moisture vapor resistance. The polymer emulsions are prepared via the direct aqueous-based free radical emulsion polymerization of ethylene with various other comonomers. The semi-crystalline aqueous-based polymer emulsions of this invention have a crystalline melting point and a crystalline heat of fusion ranging from 5 to 100 J/g. The semi-crystalline aqueous-based emulsion polymers of this invention can be used directly as a paper or paperboard coating for imparting oil, grease, solvent, water, and moisture vapor resistance. Further, the present invention provides a repulpable paper and paperboard.
本发明公开了一种纤维素产品(如纸张涂层组合物),该产品包含水基半结晶醋酸乙烯-乙烯聚合物乳液,其中含有结晶乙烯段,可用于提供耐油、耐油脂、耐溶剂、耐水和耐湿气性能。这种聚合物乳液是通过乙烯与其他各种共聚物的直接水基自由基乳液聚合制备的。本发明的半结晶水基聚合物乳液具有 5 至 100 焦耳/克的结晶熔点和结晶熔融热。本发明的半结晶水基乳液聚合物可直接用作纸或纸板涂层,以赋予纸或纸板耐油、耐油脂、耐溶剂、耐水和耐湿气的性能。此外,本发明还提供了一种可斥水的纸和纸板。