3-(2-oxo-1,2-diphenyl-5,6-dihydro-4H-cyclopenta[c]phosphol-3-yl)-1,2-diphenyl-5,6-dihydro-4H-cyclopenta[c]phosphole 2-oxide | 1222989-93-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 3-(2-oxo-1,2-diphenyl-5,6-dihydro-4H-cyclopenta[c]phosphol-3-yl)-1,2-diphenyl-5,6-dihydro-4H-cyclopenta[c]phosphole 2-oxide
• CAS: 1222989-93-6
• 化学式: C₃₈H₃₂O₂P₂
• 分子量: 582.618
• InChiKey: HCBRQJAQBYICFT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  42
• 可旋转键数：
  5
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-phenyl-1,6-heptadiyne 、 苯基二氯化磷 在 正丁基锂 、 三丁基氯化锡 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以495 mg的产率得到3-(2-oxo-1,2-diphenyl-5,6-dihydro-4H-cyclopenta[c]phosphol-3-yl)-1,2-diphenyl-5,6-dihydro-4H-cyclopenta[c]phosphole 2-oxide
  参考文献：
  名称：

  Synthesis of α,α′-Linked Oligophospholes and Polyphospholes by Using Pd−CuI-Promoted Stille-Type Coupling

  摘要：

  Palladium-copper-promoted Stille-type cross-coupling reactions between alpha-stannylphospholes and alpha-iodophospholes afforded alpha,alpha'-linked oligophospholes and polyphosphole efficiently. It has been revealed that the polyphosphole P-oxide possesses an extremely narrow band gap and a high electron-accepting ability as compared to polythiophene.

  DOI：

  10.1021/ol100926q

文献信息

• Divergent Synthesis of 2,5-Diarylphospholes Based on Cross-coupling Reactions: Substituent Effects on the Optical and Redox Properties of Benzene–Phosphole–Benzene π-Systems
  作者：Yoshihiro Matano、Yusuke Kon、Arihiro Saito、Yoshifumi Kimura、Toshihiro Murafuji、Hiroshi Imahori

  DOI：10.1246/cl.2011.919

  日期：2011.9.5

  Divergent synthesis of 2,5-diarylphosphole derivatives was achieved by using two kinds of Pd-catalyzed cross-coupling reactions. In addition, para- and P-substituent effects on the optical and redox properties of the benzene–phosphole–benzene π-systems were disclosed experimentally.

  通过使用两种Pd催化的交叉偶联反应，实现了2,5-二芳基磷烯衍生物的多样合成。此外，实验还揭示了对位和P取代基对苯–磷烯–苯π系统的光学和氧化还原特性的影响。