1,2,2,2-Tetrachlor-aethansulfensaeure-chlorid | 920-62-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫基化合物
• 英文名称: 1,2,2,2-Tetrachlor-aethansulfensaeure-chlorid
• 英文别名: 1.2.2.2-Tetrachloraethylsulfenylchlorid；Tetrachloroethylsulfenyl chloride；1,2,2,2-tetrachloroethyl thiohypochlorite
• CAS: 920-62-7
• 化学式: C₂HCl₅S
• 分子量: 234.361
• InChiKey: RUFAFKWLURMVKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,2,2,2-Tetrachlor-aethansulfensaeure-chlorid 、 Zinc methanesulfinate 生成 <3,3,3,-Trichlorpropen-(1)-yl-(1)>-methanthiolsulfonat
  参考文献：
  名称：

  烷基和芳基硫代硫酸盐。

  摘要：

  DOI：

  10.1021/jm00335a028

文献信息

• Fungicidal N-cyanoalkyl-N-haloalkylthio sulfonamides
  申请人：Chevron Research Company

  公开号：US04652556A1

  公开（公告）日：1987-03-24

  Compounds of the formula: ##STR1## wherein R is aryl of 6 to 12 carbon atoms or aralkyl of 7 to 14 carbon atoms either optionally substituted with 1 to 3 substituents independently selected from lower alkyl of 1 to 6 carbon atoms, lower alkoxy of 1 to 6 carbon atoms, lower alkylthio of 1 to 6 carbon atoms, lower alkylsulfinyl of 1 to 6 carbon atoms, lower alkylsulfonyl of 1 to 6 carbon atoms, halogen, trihalomethyl, nitro, cyano or carboxyl; alkyl of 1 to 10 carbon atoms, cycloalkyl of 3 to 10 carbon atoms, lower alkenyl of 2 to 6 carbon atoms, or lower alkynyl of 2 to 6 carbon atoms, all optionally substituted with 1 to 3 halogen atoms; lower alkoxyalkylene; lower alkylene carbalkoxy; lower alkylthioalkylene; lower alkylsulfinylalkylene; or lower alkylsulfonylalkylene; R.sup.1 and R.sup.2 are independently hydrogen, lower alkyl of 1 to 6 carbon atoms, aryl of 6 to 12 carbon atoms, or thienyl, or taken together form an alkylene bridge to give a cycloalkyl group of 3 to 10 carbon atoms; and R.sup.3 is alkyl of 1 to 3 carbon atoms substituted with 3 to 6 halogen atoms or trihalovinyl are fungicidal.

  化合物的化学式为：##STR1## 其中R为6到12个碳原子的芳基或7到14个碳原子的芳基烷基，可选择地用1到3个取代基独立地选自1到6个碳原子的低级烷基，1到6个碳原子的低级烷氧基，1到6个碳原子的低级烷硫基，1到6个碳原子的低级烷基亚磺酰基，1到6个碳原子的低级烷基磺酰基，卤素，三卤甲基，硝基，氰基或羧基；1到10个碳原子的烷基，3到10个碳原子的环烷基，2到6个碳原子的低级烯基或2到6个碳原子的低级炔基，所有这些基都可选择地用1到3个卤素原子取代；低级烷氧基烷基；低级烷基碳酸酯基；低级烷硫基烷基；低级烷基亚磺酰基烷基；或低级烷基磺酰基烷基；R.sup.1和R.sup.2独立地为氢，1到6个碳原子的低级烷基，6到12个碳原子的芳基或噻吩基，或取代成3到10个碳原子的环烷基的亚烷基桥；R.sup.3为取代有3到6个卤素原子或三卤乙烯的1到3个碳原子的烷基，则具有杀真菌作用。
• Insecticidal hydrocarbyl sulfenylmercapto pyrimidines
  申请人：Chevron Research Company

  公开号：US04016275A1

  公开（公告）日：1977-04-05

  Compounds of the formula ##STR1## wherein R, R.sup.1 and R.sup.2 are hydrogen, halogen, hydroxy, alkyl or alkenyl optionally substituted with halogen atoms and R.sup.3 is a haloalkyl, haloalkenyl or aryl group, possess morphogenetic hormonal mimetic insecticidal activity.

  公式为## STR1##的化合物，其中R，R.sup.1和R.sup.2是氢，卤素，羟基，烷基或烯基，可选择地被卤素原子取代，而R.sup.3是卤代烷基，卤代烯基或芳基，具有形态发生激素类似物杀虫活性。
• Fungicidal sulfonamide derivatives
  申请人：CHEVRON RESEARCH COMPANY

  公开号：EP0136878A2

  公开（公告）日：1985-04-10

  Fungicides which are sulfonamide derivatives are represented by the general formula; wherein R' is lower alkyl, lower alkenyl, lower alkynyl or aryl of 6 to 10 carbon atoms optionally substituted by up to 3 halogen atoms; R2 is lower alkyl, lower alkenyl, lower alkynyl or aryl of 6 to 10 carbon atoms optionally substituted by up to 3 halogen atoms or up to 3 lower alkoxy groups; and R3 is alkyl of 1 to 3 carbon atoms substituted by 3 to 6 halogen atoms or trihalovinyl. The compounds are solids which unexpectedly have higher melting points and reduced solubilities which enhance their utility as fungicides.

  属于磺酰胺衍生物的杀菌剂由通式表示； 其中 R'是 6 至 10 个碳原子的低级烷基、低级烯基、低级炔基或芳基，可选择被最多 3 个卤素原子取代；R2 是 6 至 10 个碳原子的低级烷基、低级烯基、低级炔基或芳基，可选择被最多 3 个卤素原子或最多 3 个低级烷氧基取代；R3 是 1 至 3 个碳原子的烷基，被 3 至 6 个卤素原子或三卤乙烯基取代。这些化合物是固体，意外地具有较高的熔点和较低的溶解度，从而提高了它们作为杀真菌剂的效用。
• Fungicidal n-disubstituted sulfonamides
  申请人：CHEVRON RESEARCH COMPANY

  公开号：EP0176327A1

  公开（公告）日：1986-04-02

  @ Compounds having fungicidal properties are represented by the general formula: wherein R is aryl of 6 to 12 carbon atoms or aralkyl of 7 to 14 carbon atoms, either optionally substituted by 1 to 3 substituents independently selected from lower alkyl of 1 to 6 carbon atoms, lower alkoxy of 1 to 6 carbon atoms, lower alkylthio of 1 to 6 carbon atoms, lower alkylsulfinyl of 1 to 6 carbon atoms, lower alkylsulfonyl of 1 to 6 carbon atoms, halogen, trihalomethyl, nitro, cyano and carboxyl; alkyl of 1 to 10 carbon atoms, cycloalkyl of 3 to 10 carbon atoms, tower alkenyl of 2 to 6 carbon atoms, or lower alkynyl of 2 to 6 carbon atoms, all optionally substituted by 1 to 2 halogen atoms; lower alkoxyalkylene; lower alkylene carbalkoxy; lower alkylthioalkylene; lower alkysulfinylalkylene; or lower alkylsulfonylalkylene; R' and R' are independently hydrogen, lower alkyl of 1 to 6 carbon atoms, aryl of 6 to 12 carbon atoms, or thienyl, or taken together form an alkylene bridge to give a cycloalkyl group of 3 to 10 carbon atoms; and R3 is alkyl of 1 to 3 carbon atoms substituted by 3 to 6 halogen atoms or trihalovinyl.

  @ 具有杀菌特性的化合物用通式表示： 其中 R 是 6 至 12 个碳原子的芳基或 7 至 14 个碳原子的芳烷基，任选被 1 至 3 个取代基取代，这些取代基独立选自 1 至 6 个碳原子的低级烷基、1 至 6 个碳原子的低级烷氧基、1 至 6 个碳原子的低级烷硫基、1 至 6 个碳原子的低级烷基亚磺酰基、1 至 6 个碳原子的低级烷基磺酰基、卤素、三卤甲基、硝基、氰基和羧基；1 至 10 个碳原子的烷基、3 至 10 个碳原子的环烷基、2 至 6 个碳原子的塔烯基或 2 至 6 个碳原子的低级炔基，均可选择被 1 至 2 个卤素原子取代；R'和 R'独立地为氢、1 至 6 个碳原子的低级烷基、6 至 12 个碳原子的芳基或噻吩基，或共同形成烯桥以得到 3 至 10 个碳原子的环烷基；以及 R3 为被 3 至 6 个卤素原子取代的 1 至 3 个碳原子的烷基或三卤乙烯基。
• US4016275A
  申请人：——

  公开号：US4016275A

  公开（公告）日：1977-04-05