3-chloro-4-(methylamino)aniline | 6085-54-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3-chloro-4-(methylamino)aniline
• 英文别名: 2-Chloro-N1-methylbenzene-1,4-diamine；2-chloro-1-N-methylbenzene-1,4-diamine
• CAS: 6085-54-7
• 化学式: C₇H₉ClN₂
• 分子量: 156.615
• InChiKey: XCGOCWBIFFICFZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  38
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2921590090

反应信息

• 作为反应物：
  描述：

  3-chloro-4-(methylamino)aniline 在 sodium hydroxide 、 ammonium peroxydisulfate 、 sodium dithionite 作用下， 以 乙醇 、 水 、 丙酮 为溶剂， 生成
  参考文献：
  名称：

  CH611516

  摘要：

  公开号：

文献信息

• METHOD FOR PRODUCING BIARYL COMPOUND
  申请人：Sato Koichi

  公开号：US20100087680A1

  公开（公告）日：2010-04-08

  A method for producing a biaryl compound, comprising reacting an aromatic organic compound with at least one compound selected from the group consisting of aromatic organoboron compounds and boroxine compounds, in the presence of a zero-valent nickel catalyst, phosphine ligand and base.

  一种制备双芳基化合物的方法，包括在零价镍催化剂、膦配体和碱的存在下，将芳香有机化合物与选自芳香基有机硼化合物和硼氧化物化合物组的至少一种化合物反应。
• Silver halide photographic material
  申请人：KONICA CORPORATION

  公开号：EP0207794A2

  公开（公告）日：1987-01-07

  A silver halide photographic material containing at least one of couplers represented by the general formula (I) and at least one of the compounds represented by the general formula [XII] is disclosed. Formula [I] wherein Z is a group of nonmetal atoms necessary to complete a nitrogen-containing heterocyclic ring where the ring formed by Z may be substituted; X is a hydrogen atom or a substituent capable of being released upon reaction with the oxidation product of a color developing agent and R is a hydrogen atom or substituent; wherein R21 is a hydrogen atom or a group selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and aryl group, R22 and R23 are independently selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group and an aryl group. The photographic material provides a dye-image highly stable against heat and light, and a formation of stain at a non-image area is prevented.

  本发明公开了一种卤化银感光材料，其中至少含有一种由通式（I）表示的耦合剂和至少一种由通式[XII]表示的化合物。通式 [I］ 其中 Z 是完成含氮杂环所必需的非金属原子团，由 Z 形成的环可以被取代；X 是氢原子或取代基，在与显色剂的氧化产物反应时能够被释放；R 是氢原子或取代基； 其中 R21 是氢原子或选自烷基、烯基、环烷基和芳基的基团，R22 和 R23 独立地选自烷基、烯基、环烷基和芳基的基团。 这种感光材料可提供对热和光高度稳定的染料图像，并可防止在非图像区域形成污点。
• Use of chlorites as oxidants in hair coloring
  申请人：Bristol-Myers Squibb Company

  公开号：EP0399746A1

  公开（公告）日：1990-11-28

  The invention provides compositions and methods for oxidative hair dyeing utilizing a chlorite salt as the oxidizing agent.

  本发明提供了利用亚氯酸盐作为氧化剂进行氧化染发的组合物和方法。
• Oxidative hair dyeing process with catalytic pretreatment
  申请人：Bristol-Myers Squibb Company

  公开号：EP0507448A2

  公开（公告）日：1992-10-07

  A pre-treatment solution for use in oxidatively dyeing hair comprises an aqueous solution of a complex of a transition metal ion, especially copper-II, and a chelating agent selected from 2,2′-dipyridyl and o-phenanthroline. A pretreatment process with this solution serves to conform the oxidative dyeing rate of virgin hair to that of the normally noncongruent rate of nonvirgin hair, so as to enhance the efficiency of the oxidative dyeing process, without reducing the intensity or variety of color. A hair treatment package in kit form comprising the aqueous solution and an oxidative hair dye mixture is also disclosed.

  一种用于氧化染发的预处理溶液包括过渡金属离子（尤其是铜Ⅱ）与选自 2,2′-二吡啶基和邻菲罗啉的螯合剂的络合物的水溶液。 用这种溶液进行预处理，可使原生发的氧化染色速率与非原生发的通常不一致的速率相一致，从而提高氧化染色过程的效率，而不降低颜色的强度或种类。此外，还公开了一种试剂盒形式的头发处理包，其中包括水溶液和氧化染发混合物。
• Use of metal salts and chelates together with chlorites as oxidants in hair coloring
  申请人：Bristol-Myers Squibb Company

  公开号：EP0621029A1

  公开（公告）日：1994-10-26

  An aqueous hair dye composition containing from about 0.05% to 20% by weight of sodium chlorite; from about 0.001% to 5% by weight of a water soluble copper, iron, manganese or cobalt salt, a chelate of said salt, or a mixture thereof, and an oxidative hair dye precursor in an amount which will oxidize to form a tinctorially effective amount of a hair dye. Also provided are a packaged form of the components of the composition and a method of dyeing hair with the composition.

  一种水性染发组合物，含有约 0.05%至 20%（按重量计）的亚氯酸钠；约 0.001%至 5%（按重量计）的水溶性铜、铁、锰或钴盐，所述盐的螯合物，或它们的混合物，以及氧化性染发剂前体，其用量可氧化形成锡有效量的染发剂。此外，还提供了组合物组分的包装形式和用组合物染发的方法。