p-(methylammonio)anilinium dichloride | 5395-70-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: p-(methylammonio)anilinium dichloride
• 英文别名: N-methyl-p-phenylenediamine; dihydrochloride；N-Methyl-p-phenylendiamin; Dihydrochlorid；N-methylparaphenylenediamine dihydrochloride；N-Methyl-p-phenylenediamine dihydrochloride；4-N-methylbenzene-1,4-diamine;hydrochloride
• CAS: 5395-70-0
• 化学式: C₇H₁₀N₂*2ClH
• 分子量: 195.092
• InChiKey: IJJSFSXLZYFTKV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.73
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  38
• 氢给体数：
  3
• 氢受体数：
  2

安全信息

• 安全说明：
  S26,S36/37/39
• 危险类别码：
  R20/21/22,R36/37/38
• 海关编码：
  2921590090

SDS

Name:	N-Methyl-p-phenylenediamine dihydrochloride 98% (titr.) Material Safety Data Sheet
Synonym:
CAS:	5395-70-0

Section 1 - Chemical Product MSDS Name:N-Methyl-p-phenylenediamine dihydrochloride 98% (titr.) Material Safety Data Sheet
Synonym:

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
5395-70-0	N-Methyl-p-phenylenediamine dihydrochl	98	unlisted

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
No information regarding skin irritation and other potential effects was found.
Ingestion:
The toxicological properties of this substance have not been fully investigated. May cause central nervous system effects.
Inhalation:
The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 5395-70-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H10N2.2HCl
Molecular Weight: 195.09

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 5395-70-0 unlisted.
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
N-Methyl-p-phenylenediamine dihydrochloride - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 5395-70-0: No information available.
Canada
CAS# 5395-70-0 is listed on Canada's NDSL List.
CAS# 5395-70-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5395-70-0 is listed on the TSCA inventory.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  p-(methylammonio)anilinium dichloride 在 palladium on activated charcoal 4-二甲氨基吡啶 、 氢气 作用下， 以 吡啶 、 甲醇 、 乙腈 为溶剂， 8.0~25.0 ℃ 、101.33 kPa 条件下， 反应 26.0h， 生成 (4-甲氨基苯基)氨基甲酸叔丁酯
  参考文献：
  名称：

  Lurdes, M.; Almieda, S.; Grehn, Leif, Journal of the Chemical Society. Perkin transactions I, 1988, p. 1905 - 1912

  摘要：

  DOI：

文献信息

• Cyan couplers and colour photographic materials containing them
  申请人：KONICA CORPORATION

  公开号：EP0067689A1

  公开（公告）日：1982-12-22

  A silver halide photosensitive material is disclosed for color photography which comprises a novel phenol type cyan coupler having the formula: where X1, X2, Y, Z and n have specific values. The cyan coupler mentioned above is a novel cyan dye image-forming coupler and the photosensitive material containing the same according to the present invention has removed the various drawbacks in the prior art.

  本发明公开了一种用于彩色摄影的卤化银感光材料，它包括一种新型苯酚型青色耦合剂，该耦合剂的化学式为 其中 X1、X2、Y、Z 和 n 具有特定值。 上述青色耦合剂是一种新型的青色染料图像形成耦合剂，根据本发明，含有这种耦合剂的感光材料消除了现有技术中的各种缺点。
• Method and material for the formation of silver halide color photographic image
  申请人：KONICA CORPORATION

  公开号：EP0073146A1

  公开（公告）日：1983-03-02

  A novel class of phenol cyan couplers are described. These couplers have in the two position a phenyl ureido group substituted by an alkyl, aryl, heterocyclic, hydroxy, alkoxy, aryloxy, acyloxy, alkyl-thio, acylamino or sulfonamide group; which has in the four position thereof a hydrogen atom or an atom or group capable of being eliminated during coupling with the oxidation product of a color developing agent; and which has in the five position thereof an acylamino group.

  本文描述了一类新型的苯酚氰基偶联剂，这些偶联剂在 2 位上有一个被烷基、芳基、杂环基、羟基、烷氧基、芳氧基、酰氧基、烷硫基、酰氨基或磺酰胺基取代的苯基脲基；在 4 位上有一个氢原子或在与显色剂的氧化产物偶联时能够被消除的原子或基团；在 5 位上有一个酰氨基。
• Light-sensitive silver halide color photographic material
  申请人：KONICA CORPORATION

  公开号：EP0087930A1

  公开（公告）日：1983-09-07

  Disclosed is a light-sensitive silver halide color photographic material having at least one light-sensitive silver halide emulsion layer on a support, characterized in that said light-sensitive silver halide emulsion layer contains a cyan coupler represented by the formula [I] shown below, and said light-sensitive silver halide emulsion layer and/or a layer contiguous to said light-sensitive silver halide emulsion layer contains a colored cyan coupler represented by the formula [II]: Formula [I]: wherein X, R, and R2 are as defined in the specification; Formula [II]: wherein (Coup-)c, L, Q1, Q2, M, j, and G are as defined in the specification.

  本发明公开了一种感光卤化银彩色感光材料，该材料在支撑体上具有至少一个感光卤化银乳剂层，其特征在于所述感光卤化银乳剂层含有如下式[I]表示的青色耦合剂，并且所述感光卤化银乳剂层和/或与所述感光卤化银乳剂层相邻的层含有如下式[II]表示的彩色青色耦合剂： 式[I]：其中 X、R 和 R2 如说明书中所定义； 式[II]：其中 (Coup-)c、L、Q1、Q2、M、j 和 G 如说明书中所定义。
• Silver halide photosensitive materials for color photography
  申请人：KONICA CORPORATION

  公开号：EP0105991A1

  公开（公告）日：1984-04-25

  A silver halide photosensitive material is disclosed for color photography which comprises a phenol type cyan coupler having the formula: wherein X1 is -CN,-COOR1,-COR1,-SO2OR1,-SO2R1, in which R1 is an alkyl group or an aryl group and R is a hydrogen atom, an alkyl group or an aryl group; X2 is a hydrogen atom, a halogen atom, a hydroxy group, a nitro group or a monovalent organic group; Y, which is optionally present, is a non-metallic group which forms a 5- or 6-membered condensed ring as indicated by the dotted lines; Z is a hydrogen atom or a group removable upon coupling with an oxidation product of a color developing agent; Ball isa ballastgroup; and n is 0 or and integer from 1 to 4 inclusive such that, when n is 2 or more, each X2 may be the same or different.

  本发明公开了一种用于彩色摄影的卤化银感光材料，该材料包含一种苯酚型青色耦合剂，其化学式为 其中 X1 是-CN、-COOR1、-COR1、-SO2OR1、-SO2R1、 其中 R1 是烷基或芳基，R 是氢原子、烷基或芳基； X2 是氢原子、卤素原子、羟基、硝基或一价有机基团； Y 是一个非金属基团，如虚线所示，形成一个 5 或 6 元缩合环； Z 是氢原子或与显色剂的氧化产物偶联后可去除的基团； Ball 是镇流器基团 n 为 0 或 1 至 4 的整数，当 n 为 2 或 2 以上时，每个 X2 可以相同或不同。
• Method of improving the light resistance of a dye image
  申请人：KONICA CORPORATION

  公开号：EP0137271A2

  公开（公告）日：1985-04-17

  There is disclosed a photographic element comprising a support having thereon a layer containing an anilino-type magenta coupler, wherein said layer comprises an organic solvent having a dielectric constant of not greater than 6.5 and a metallic complex having the following formula (1), (11) or (III) : wherein M is nickel, copper, cobalt, palladium or platinum; X, and X2 each is hydrogen, sulfur or -NR5, wherein R5 is hydrogen or an alkyl, aryl or hydroxyl radical; X3 is a hydroxyl or mercapto radical; Y is oxygen or sulfur; R1, R2, R3 and R4 each is hydrogen atom, a halogen, a cyano radical, or an alkyl, aryl cycloalkyl or heterocyclic radical which each is bonded directly or through a divalent combining radical to a carbon atom, provided at least one of the R1-R2 and R3-R4 combinations is allowed to form a 5- or 6-member cyclic ring by combining with the carbon atoms which are bonded with each other; and z is a compound coordinatable to M. By incorporating of such a metallic complex compound there can be improved the light resistance of a dye image formed with said photographic element.

  本发明公开了一种照相元件，该元件包括一个支架，支架上有一层含有苯胺型品红耦合剂的层，其中所述层包括介电常数不大于 6.5 的有机溶剂和具有下式 (1)、(11) 或 (III) 的金属络合物： 其中 M 是镍、铜、钴、钯或铂；X 和 X2 各自是氢、硫或-NR5，其中 R5 是氢或烷基、芳基或羟基；X3 是羟基或巯基；Y 是氧或硫；R1、R2、R3 和 R4 各自是氢原子、卤素、氰基或烷基、芳基环烷基或杂环基，它们各自直接或通过二价结合基键合到碳原子上，条件是 R1-R2 和 R3-R4 组合中至少有一个可通过与相互键合的碳原子结合形成 5 或 6 元环；以及 z 是可与 M 配位的化合物。通过加入这样的金属复合物，可以提高用所述感光元件形成的染料图像的耐光性。