HF2-radical | 12528-21-1

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 其他非金属卤化物
• 英文名称: HF2-radical
• CAS: 12528-21-1
• 化学式: F₂H
• 分子量: 39.0047
• InChiKey: OSCYTRCYWNNKRF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氢氟酸 、 fluorine 以0%的产率得到HF2-radical
  参考文献：
  名称：

  A search for the HF₂ and HClF neutral free radicals isolated in argon matrices

  摘要：

  A systematic search has been carried out for the neutral species FHF and FHCl isolated in argon matrices at 14 K. The synthesis of these species was attempted by the photolysis of F2 in the presence of either HF or HCl, either concurrent with, or after deposition into the low temperature matrix. Infrared spectra of these samples gave no evidence for the formation of a species of the form FHF, while evidence was demonstrated for a weakly bound complex between HF and Cl, but with a very different spectrum and structure than the corresponding FHCl− anion. These results are in general agreement with the detailed theoretical calculations that have been performed on these systems.

  DOI：

  10.1063/1.436315

文献信息

• Infrared spectra of diatomic halogen complexes with hydrogen fluoride in solid argon and neon
  作者：Rodney D. Hunt、Lester Andrews

  DOI：10.1021/j100324a016

  日期：1988.6
• A search for the HF₂ and HClF neutral free radicals isolated in argon matrices
  作者：Bruce S. Ault

  DOI：10.1063/1.436315

  日期：1978.5

  A systematic search has been carried out for the neutral species FHF and FHCl isolated in argon matrices at 14 K. The synthesis of these species was attempted by the photolysis of F2 in the presence of either HF or HCl, either concurrent with, or after deposition into the low temperature matrix. Infrared spectra of these samples gave no evidence for the formation of a species of the form FHF, while evidence was demonstrated for a weakly bound complex between HF and Cl, but with a very different spectrum and structure than the corresponding FHCl− anion. These results are in general agreement with the detailed theoretical calculations that have been performed on these systems.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: SVol.3, 2.6.1, page 329 - 329
  作者：

  DOI：——

  日期：——