[Cu(1,2-diaminophenyl-N,N'-bis-(2-pyridinecarboxaldimine))(NO3)2] | 1000062-59-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Cu(1,2-diaminophenyl-N,N'-bis-(2-pyridinecarboxaldimine))(NO3)2]
• CAS: 1000062-59-8
• 化学式: C₁₈H₁₄CuN₆O₆
• 分子量: 473.892
• InChiKey: WBDMGCAMJFPRTD-MYHDMYFSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) nitrate trihydrate 、 bis(2-pyridylcarbonylaldehyde)-o-phenylenediamine 以 甲醇 为溶剂， 以55%的产率得到[Cu(1,2-diaminophenyl-N,N'-bis-(2-pyridinecarboxaldimine))(NO3)2]
  参考文献：
  名称：

  Synthesis and physico-chemical studies on complexes of 1,2-diaminophenyl-N,N′-bis-(2-pyridinecarboxaldimine), (L): A spectroscopic approach on binding studies of DNA with the copper complex

  摘要：

  The Schiff base ligand, 1,2-diaminophenyl-N,N'-bis-(2-pyridinecarboxaldimine), (L) has been synthesized by the reaction of o-phenydo lenediamine and 2-pyridinecarboxaldehyde, and a series of mononuclear complexes of the type [ML(NO3)(2)] (M = Co(II), Ni(II), Cu(II) and Zn(II)] has also been synthesized. The formation of the Schiff base ligand (L) and its complexes have been envisaged from IR, H-1 and C-13 NMR studies. The absorption band observed in the electronic spectra and magnetic moment values confirm an octahedral environment around the metal ion. The molar conductivity measurements confirm the non-ionic character of these complexes. Fluorescence and UV-Vis absorption studies performed on the Cu(II) complex revealed a significant binding ability to DNA. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.08.032