Cu(acetylacetonato aniline acetohydrazone)(acetate)2(H2O)*H2O | 1248714-72-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Cu(acetylacetonato aniline acetohydrazone)(acetate)2(H2O)*H2O
• CAS: 1248714-72-8
• 化学式: C₁₇H₂₅CuN₃O₇*H₂O
• 分子量: 464.963
• InChiKey: JQCCTPWROFZAQG-GFVMCJLESA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Cu(acetylacetonato aniline acetohydrazone)(acetate)2(H2O)*H2O 以 neat (no solvent) 为溶剂， 生成 copper(II) oxide
  参考文献：
  名称：

  Thermal studies of acetylacetonato aniline acetohydrazone and complexes with divalent ions of Mn, Co, Ni and Cu

  摘要：

  The thermal studies of acetylacetonato aniline acetohydrazone and its divalent metal ions Mn2+, Co2+. Ni2+ and Cu2+ complexes were studied and discussed in terms of its molecular structure and type of metal ions. TG curves display mostly three steps of thermal decomposition. The first step is due to dehydration followed by the elimination of the anions from the complexes. The anhydrous free anion complexes undergo further decomposition forming metal oxides as final products. The activation energies E-a were evaluated and discussed in accordance with the structure of the complexes, which was assured, by elemental analyses and IR spectra. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.tca.2010.05.002
• 作为产物：
  描述：

  acetylacetonato aniline acetohydrazone tetrahydrate 、 水 、 copper diacetate 以 not given 为溶剂， 生成 Cu(acetylacetonato aniline acetohydrazone)(acetate)2(H2O)*H2O
  参考文献：
  名称：

  Thermal studies of acetylacetonato aniline acetohydrazone and complexes with divalent ions of Mn, Co, Ni and Cu

  摘要：

  The thermal studies of acetylacetonato aniline acetohydrazone and its divalent metal ions Mn2+, Co2+. Ni2+ and Cu2+ complexes were studied and discussed in terms of its molecular structure and type of metal ions. TG curves display mostly three steps of thermal decomposition. The first step is due to dehydration followed by the elimination of the anions from the complexes. The anhydrous free anion complexes undergo further decomposition forming metal oxides as final products. The activation energies E-a were evaluated and discussed in accordance with the structure of the complexes, which was assured, by elemental analyses and IR spectra. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.tca.2010.05.002