N-phenyl-N-(4-phenylphenyl)-N-(9-phenyl-9H-carbazol-3-yl)amine | 1414937-44-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-phenyl-N-(4-phenylphenyl)-N-(9-phenyl-9H-carbazol-3-yl)amine
• 英文别名: N,9-diphenyl-N-(4-phenylphenyl)carbazol-3-amine
• CAS: 1414937-44-2
• 化学式: C₃₆H₂₆N₂
• 分子量: 486.616
• InChiKey: GHJIDUUIFVJAHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.9
• 重原子数：
  38
• 可旋转键数：
  5
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  8.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-溴-N-苯基咔唑 、 N-苯基-4-联苯胺 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ sodium t-butanolate 作用下， 以 xylene 为溶剂， 反应 6.5h， 以91%的产率得到N-phenyl-N-(4-phenylphenyl)-N-(9-phenyl-9H-carbazol-3-yl)amine
  参考文献：
  名称：

  Carbazole Compound, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device

  摘要：

  提供一种由一般式（G1）表示的咔唑化合物。在该式中，α代表苯基，Ar1代表具有1至6个碳原子的烷基基团、取代或未取代的苯基、取代或未取代的萘基团或取代或未取代的菲基团，Ar2代表氢、取代或未取代的苯基、取代或未取代的萘基团或取代或未取代的菲基团，Ar3代表取代或未取代的苯基、取代或未取代的萘基团或取代或未取代的菲基团，R1代表氢、具有1至6个碳原子的烷基基团或取代或未取代的苯基。此外，n为0或1。

  公开号：

  US20120302762A1

文献信息

• Light-Emitting Element, Light-Emitting Device, Electronic Device, Lighting Device, and Novel Organic Compound
  申请人：Takeda Kyoko

  公开号：US20130048964A1

  公开（公告）日：2013-02-28

  A light-emitting element includes an EL layer between a pair of electrodes. The EL layer contains a first compound and a second compound. The first compound is a phosphorescent iridium metal complex having a LUMO level of greater than or equal to −3.5 eV and less than or equal to −2.5 eV, and the second compound is an organic compound having a pyrimidine skeleton. The light-emitting element includes an EL layer between a pair of electrodes. The EL layer contains a first compound and a second compound. The first compound is a phosphorescent iridium metal complex having a diazine skeleton, and the second compound is an organic compound having a pyrimidine skeleton.

  一种发光元件包括两个电极之间的EL层。EL层包含第一化合物和第二化合物。第一化合物是一种具有大于或等于-3.5电子伏特且小于或等于-2.5电子伏特的荧光铱金属配合物，第二化合物是具有嘧啶骨架的有机化合物。发光元件包括两个电极之间的EL层。EL层包含第一化合物和第二化合物。第一化合物是具有嘧啶骨架的荧光铱金属配合物，第二化合物是具有嘧啶骨架的有机化合物。
• Carbazole compound, light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Osaka Harue

  公开号：US09079855B2

  公开（公告）日：2015-07-14

  A carbazole compound represented by General Formula (G1) is provided. In the formula, α represents a phenylene group, Ar1 represents an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, or a substituted or unsubstituted phenanthryl group, Ar2 represents hydrogen, a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, or a substituted or unsubstituted phenanthryl group, Ar3 represents a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, or a substituted or unsubstituted phenanthryl group, and R1 represents hydrogen, an alkyl group having 1 to 6 carbon atoms, or a substituted or unsubstituted phenyl group. Further, n is 0 or 1.

  提供了一个通式（G1）表示的咔唑化合物。在该式中，α代表苯基，Ar1代表具有1至6个碳原子的烷基基团、取代或未取代的苯基、取代或未取代的萘基或取代或未取代的菲基；Ar2代表氢、取代或未取代的苯基、取代或未取代的萘基或取代或未取代的菲基；Ar3代表取代或未取代的苯基、取代或未取代的萘基或取代或未取代的菲基；R1代表氢、具有1至6个碳原子的烷基基团或取代或未取代的苯基。此外，n为0或1。
• Organic electroluminescent device
  申请人：Samsung Display Co., Ltd.

  公开号：US10184078B2

  公开（公告）日：2019-01-22

  An organic electroluminescent device of which emission life may be improved. The organic electroluminescent device includes an anode, an emission layer, and an anode-side hole transport layer provided between the anode and the emission layer and including an anode-side hole transport material. An electron accepting material is doped in the anode-side hole transport layer. An intermediate hole transport material layer is provided between the anode-side hole transport layer and the emission layer and includes an intermediate hole transport material, and an emission layer-side hole transport layer is provided between the intermediate hole transport material layer and the emission layer and adjacent to the emission layer. The emission layer-side hole transport layer includes an emission layer-side hole transport material represented by the following Formula 1.

  一种可提高发射寿命的有机电致发光器件。该有机电致发光器件包括阳极、发射层和阳极侧空穴传输层，阳极侧空穴传输层位于阳极和发射层之间，包括阳极侧空穴传输材料。阳极侧空穴传输层中掺杂有电子接受材料。在阳极侧空穴传输层和发射层之间设有中间空穴传输材料层，其中包括中间空穴传输材料；在中间空穴传输材料层和发射层之间设有发射层侧空穴传输层，该层与发射层相邻。发射层侧空穴传输层包括由下式 1 表示的发射层侧空穴传输材料。
• Fluorene derivative, light-emitting elements, light-emitting device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10553797B2

  公开（公告）日：2020-02-04

  An object is to provide a light-emitting element having high light-emission efficiency by provision of a novel fluorene derivative as represented by General Formula (G1) below. In the formula, R1 to R8 independently represent any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted biphenyl group. Further, α1 to α4 independently represent any of a substituted or unsubstituted arylene group having 6 to 12 carbon atoms. Furthermore, Ar1 and Ar2 independently represent any of an aryl group having 6 to 13 carbon atoms in a ring and Ar3 represents an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms. J, k, m, and n each independently represent 0 or 1.

  目的是通过提供一种新型芴衍生物，如下文通式 (G1) 所示，提供一种具有高发光效率的发光元件。 式中，R1 至 R8 独立地代表氢原子、具有 1 至 6 个碳原子的烷基、取代或未取代的苯基、取代或未取代的联苯基中的任意一种。此外，α1 至 α4 独立地代表具有 6 至 12 个碳原子的取代或未取代的芳烯基团中的任一个。此外，Ar1 和 Ar2 独立地代表在环上具有 6 至 13 个碳原子的芳基，Ar3 代表具有 1 至 6 个碳原子的烷基或具有 6 至 12 个碳原子的取代或未取代的芳基。J、k、m 和 n 各自独立地代表 0 或 1。
• Organic light-emitting device
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US10756274B2

  公开（公告）日：2020-08-25

  An organic light-emitting device including a first electrode; a second electrode; emission units stacked between the first electrode and the second electrode and including at least one emission layer; and charge generation layers between two adjacent emission units, the charge generation layers each including an n-type charge generation layer and p-type charge generation layer, a maximum emission wavelength of light emitted by at least one of the emission units is different from that of another emission unit, one n-type charge generation layer includes a first compound and a metal-containing material, the first compound being represented by Formula 1, the p-type charge generation layers include an amino group-free compound, at least one of the emission units further includes a hole transporting (HT)-emission auxiliary layer on a first electrode side thereof, and the HT-emission auxiliary layer includes at least one second compound, the second compound being represented by Formula 2:

  一种有机发光器件，包括第一电极；第二电极；堆叠在第一电极和第二电极之间并包括至少一个发射层的发射单元；相邻两个发射单元之间的电荷发生层，电荷发生层各包括一个 n 型电荷发生层和一个 p 型电荷发生层，至少一个发射单元发出的光的最大发射波长不同于另一个发射单元，其中一个 n 型电荷发生层包括一个第一化合物和一个含金属材料、第一化合物由式 1 表示，p 型电荷发生层包括不含氨基的化合物，至少一个发射单元进一步包括位于其第一电极侧的空穴传输（HT）发射辅助层，HT-发射辅助层包括至少一种第二化合物，第二化合物由式 2 表示：