4,4'-di(4-hydroxybenzylideneamino)triphenylamine | 1226915-27-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4,4'-di(4-hydroxybenzylideneamino)triphenylamine
• CAS: 1226915-27-0
• 化学式: C₃₂H₂₅N₃O₂
• 分子量: 483.569
• InChiKey: DAIBTXQYRLYYBW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.07
• 重原子数：
  37.0
• 可旋转键数：
  7.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  68.42
• 氢给体数：
  2.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  N1,N1-二(4-氨基苯基)苯-1,4-二胺 、 对羟基苯甲醛 以 乙醇 为溶剂， 以96.9%的产率得到4,4'-di(4-hydroxybenzylideneamino)triphenylamine
  参考文献：
  名称：

  Novel blue and red electrochromic poly(azomethine ether)s based on electroactive triphenylamine moieties

  摘要：

  Two series of red and blue electrochromic aromatic poly(azomethine ether)s (PAMEs) containing electroactive triphenylamine (TPA) moieties in the backbone were prepared from the high-temperature polycondensation reactions of newly azomethine-triphenylamine (AM-TPA)-based biphenol monomers, 4,4'-di(4-hydroxybenzylideneamino) triphenylamine (3) and 4,4'-di(4-hydroxybenzylideneamino)-4 ''-methoxytriphenylamine (4), with difluoro compounds, respectively. The obtained polymers were readily soluble in many organic solvents and showed useful levels of thermal stability associated with high softening temperatures (215-240 degrees C) and high char yields (higher than 64% at 800 degrees C in nitrogen). In addition, the polymer films showed reversible electrochemical oxidation with high contrast ratio and unique anodic blue/red electrochromic behaviors. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.orgel.2009.11.009