dinitrato[2,3:9,10-biphenyldiamine-5,7,12,14-tetramethyl-1,4,8,11-tetraazacycloteradecane-4,7,11,14-tetraene]zinc(II) | 1338990-09-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: dinitrato[2,3:9,10-biphenyldiamine-5,7,12,14-tetramethyl-1,4,8,11-tetraazacycloteradecane-4,7,11,14-tetraene]zinc(II)
• CAS: 1338990-09-2
• 化学式: C₃₄H₃₆N₁₀O₆Zn
• 分子量: 746.113
• InChiKey: WPUFYAZVINXTIZ-PWXYMGBBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3,3'-二氨基联苯胺 、 zinc(II) nitrate hexahydrate 、 乙酰丙酮 以 水 、 乙腈 为溶剂， 以56%的产率得到dinitrato[2,3:9,10-biphenyldiamine-5,7,12,14-tetramethyl-1,4,8,11-tetraazacycloteradecane-4,7,11,14-tetraene]zinc(II)
  参考文献：
  名称：

  Template Synthesis and Physicochemical Studies of 14-Membered Functionalized Pendant Arm Schiff-Base Macrocyclic Complexes of Co(II), Ni(II), Cu(II), and Zn(II): DNA Binding Studies on a Cu(II) Complex

  摘要：

  A series of functional pendant armed 14-membered Schiff-base macrocyclic complexes [ML(NO3)(2)], where M = Co(II), Ni(II), Cu(II), and Zn(II), has been synthesized by template condensation of 3,3'-diaminobenzidene and acetylacetone. The complexes have been characterized by elemental analyses, molar conductance measurements, magnetic susceptibility measurements, and electrospray ionization (ESI) mass, H-1-nuclear magnetic resonance (NMR), infrared (IR), electronic, and electron paramagnetic resonance (EPR) spectral studies. The results of elemental analyses, ESI mass spectroscopy, and conductivity measurements confirmed the stoichiometry of the complexes, while the characteristic absorption bands and resonance peaks in IR and NMR spectra confirmed the formation of frameworks of complexes. The molar conductance measurements of the complexes in dimethyl sulfoxide (DMSO) correspond to being non-electrolyte in nature. However, the overall geometry of the complexes has been assigned on the positions of bands in electronic spectra and magnetic moment data. The distortion in Cu(II) complexes has been deduced on the basis of EPR data. Absorption and fluorescence studies on the Cu(II) complex show a significant binding to CT DNA.

  DOI：

  10.1080/15533174.2011.591345