(N,N'-bis([2-(1,1-dimethylethylthio)phenyl]methylene)-ethane-1,2-diamine-S,S',N,N')copper(I) perchlorate | 181118-48-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: (N,N'-bis([2-(1,1-dimethylethylthio)phenyl]methylene)-ethane-1,2-diamine-S,S',N,N')copper(I) perchlorate
• CAS: 181118-48-9
• 化学式: C₂₄H₃₂CuN₂S₂*ClO₄
• 分子量: 575.66
• InChiKey: OZQBMDLSIBIWQB-QZZBCIHISA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetrakis(acetonitrile)copper(I) perchlorate 、 N,N'-bis([2-(1,1-dimethylethylthio)phenyl]methylene)-ethane-1,2-diamine 以 乙二醇甲醚 为溶剂， 以78%的产率得到(N,N'-bis([2-(1,1-dimethylethylthio)phenyl]methylene)-ethane-1,2-diamine-S,S',N,N')copper(I) perchlorate
  参考文献：
  名称：

  Reactivity of copper(I) and (II) and zinc(II) complexes of bis-(t-butyl)thiosalen and the crystal structure of the stable Cu(I) complex

  摘要：

  A study of the de-t-butylation properties of the N2S2 ligand N,N'-bis{[2-(1,1-dimethylethylthio)phenyl]methylene}-ethane-1,2-diamine (L-1) has shown that in contrast to its behaviour with Ni(II) it will not undergo de-t-butylation, using the conventional conditions, with Cu(I) or Zn(II) and not cleanly with Cu(II). The air stable perchlorate salt of the Cu(I) complex of L-1 has been isolated and its crystal structure determined. The complex has a distorted tetrahedral structure in which the ligand binds in such a way as to produce the diastereomeric form of the complex in which both t-butyl groups are directed away from the centre of the molecule and from each other. Cyclic voltammetry in nitromethane indicated that the Cu(II) complex of L-1 is chemically unstable, which was verified during synthetic studies in which it was seen to be prone to both hydrolysis and partial de-t-butylation. Spectroscopic and conductometric evidence suggest that in the ZnCl2 complex of L-1 coordination of chloride occurs to the exclusion of both thioether moieties.

  DOI：

  10.1016/s0020-1693(96)05496-5