(5R,8R,9S,10S,13S,14S,17R)-16-(Bis-methylsulfanyl-methylene)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-ol | 91003-01-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: (5R,8R,9S,10S,13S,14S,17R)-16-(Bis-methylsulfanyl-methylene)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-ol
• CAS: 91003-01-9
• 化学式: C₂₂H₃₆OS₂
• 分子量: 380.659
• InChiKey: KHBYBFJACOGDLI-HGHPPZQBSA-N

反应信息

• 作为产物：
  描述：

  (5R,8R,9S,10S,13S,14S)-16-(Bis-methylsulfanyl-methylene)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-one 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 以87%的产率得到(5R,8R,9S,10S,13S,14S,17R)-16-(Bis-methylsulfanyl-methylene)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-ol
  参考文献：
  名称：

  .alpha.-Oxo ketene dithioacetal chemistry. 3. A regio- and stereospecific lithium aluminum hydride reduction resulting in the formation of stereochemically defined .beta.-alkyl .gamma.-bis(methylthio) alcohols

  摘要：

  DOI：

  10.1021/jo00190a040