4-(苯并噻唑-2-基硫)-2,6-甲基吗啉 | 102-78-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 中文名称: 4-(苯并噻唑-2-基硫)-2,6-甲基吗啉
• 中文别名: 2-(2,6-二甲基吗啉-4-基)硫基-1,3-苯并噻唑
• 英文名称: 2-(2,6-Dimethylmorpholinothio)benzothiazol
• 英文别名: 2-(2,6-Dimethylmorpholinosulfenyl)-benzothiazol；2-(2,6-dimethyl-morpholin-4-ylsulfanyl)-benzothiazole；4-(benzothiazole-2-sulfenyl)-2,6-dimethyl-morpholine；4-(Benzothiazol-2-sulfenyl)-2,6-dimethyl-morpholin；4-(benzothiazol-2-ylthio)-2,6-dimethylmorpholine；4-(1,3-benzothiazol-2-ylsulfanyl)-2,6-dimethylmorpholine
• CAS: 102-78-3
• 化学式: C₁₃H₁₆N₂OS₂
• 分子量: 280.415
• InChiKey: DNPSGCQXSGVQSK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  78.9
• 氢给体数：
  0
• 氢受体数：
  5

安全信息

• 海关编码：
  2934999090

反应信息

• 作为产物：
  描述：

  2-巯基苯并噻唑 、 2,6-二甲基吗啉 在 sodium hypochlorite 作用下， 生成 4-(苯并噻唑-2-基硫)-2,6-甲基吗啉
  参考文献：
  名称：

  Derivatives of Thiazolethiols

  摘要：

  DOI：

  10.1021/ja01576a054

文献信息

• FUNCTIONAL REINFORCING FILLERS MODIFIED WITH ALKENYLALKOXYSILANE AND PREPARING METHOD OF THE SAME
  申请人：KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

  公开号：US20140102332A1

  公开（公告）日：2014-04-17

  Disclosed are a functional reinforcing filler including inorganic particles surface-modified with an alkenylsilanol obtained by hydrolyzing an alkenylalkoxysilane compound, and a method for preparing the same. Since the disclosed functional reinforcing filler has a functional group having a double bond, it has good reactivity for styrene-butadiene rubber and sulfur. Thus, when used as a functional reinforcing filler in the manufacture of rubber, it allows improvement of physical properties through adjustment of the addition amount of sulfur without additional use of the coupling agent. In addition, because of superior hydrolysis reactivity, the problem of alcohol can be solved and a rubber mixture with long scorch time can be prepared. In particular, when the functional reinforcing filler of the present invention is used in the manufacture of tires, improvement in modulus, tensile strength, rotational resistance and wet traction performance can be expected.

  本发明公开了一种功能性增强填料，其中包括经过烯基硅醇表面修饰的无机颗粒，该烯基硅醇是通过水解烯基烷氧基硅烷化合物得到的，并且公开了其制备方法。由于所公开的功能性增强填料具有具有双键的功能性基团，因此对于苯乙烯-丁二烯橡胶和硫具有良好的反应性。因此，在橡胶制造中使用作为功能性增强填料时，可以通过调整硫的添加量来改善物理性能，而无需额外使用偶联剂。此外，由于其优异的水解反应性，可以解决醇的问题，并制备具有长烧伤时间的橡胶混合物。特别是，当本发明的功能性增强填料用于轮胎制造时，可以预期提高模量、拉伸强度、旋转阻力和湿地牵引性能。
• Vulcanized olefin-based rubber composition
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0103695A1

  公开（公告）日：1984-03-28

  A vulcanized olefin-based rubber composition is disclosed which is produced by vulcanizing an olefin-based rubber composition with a sulfur-containing substance alone or with a sulfur-containing substance and a vulcanization accelerator in combination. The olefin-based rubber composition is composed of (A) olefin-based rubber composed mainly of ethylene and propylene and (B) aluminium or an aluminium alloy in the form of powder, fiber, or flake, or being composed of (A) olefin-based rubber composed mainly of ethylene and propylene, (B) aluminium or an aluminium alloy in the form of powder, fiber, orflake, and (C) electrically-conductive carbon black, and said sulfur-containing substance being selected from the group consisting of a sulfur-based vulcanizing agent and a sulfur-releasing agent. The composition of this invention is superior in the shielding of electromagnetic waves.

  本发明公开了一种硫化烯烃基橡胶组合物，它是通过将烯烃基橡胶组合物单独与含硫物质或与含硫物质和硫化促进剂混合硫化而制成的。烯烃基橡胶组合物由(A)主要由乙烯和丙烯组成的烯烃基橡胶和(B)粉末、纤维或薄片形式的铝或铝合金组成，或由(A)主要由乙烯和丙烯组成的烯烃基橡胶组成、(B) 粉末、纤维或薄片形式的铝或铝合金，以及 (C) 导电炭黑，所述含硫物质选自硫基硫化剂和脱硫剂组成的组。 本发明的组合物在屏蔽电磁波方面性能优越。
• Scintillation converter for neutron radiography
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0150863A2

  公开（公告）日：1985-08-07

  A scintillation converter for neutron radiography is described, comprising a composition formed of components (A) 100 parts by weight of an olefin rubber made mainly of ethylene and propylene, (B) from 100 to 400 parts by weight of at least one inorganic compound selected from the group consisting of inorganic boron compounds and inorganic lithium compounds, and (C) from 100 to 600 parts by weight of a zinc sulfide-base fluorescent material. This scintillation converter is not only superior in radiation-sensitive performance, but also has high elasticity and superior abrasion resistance.

  描述了一种用于中子射线照相术的闪烁转换器，它由以下成分组成：(A) 100 份（按重量计）主要由乙烯和丙烯制成的烯烃橡胶，(B) 100 至 400 份（按重量计）至少一种无机化合物，这些无机化合物选自无机硼化合物和无机锂化合物组成的组，以及 (C) 100 至 600 份（按重量计）硫化锌基荧光材料。这种闪烁转换器不仅辐射敏感性能优越，而且具有高弹性和出色的耐磨性。
• COMPOSITION FOR OPTICAL MATERIAL
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1326095A1

  公开（公告）日：2003-07-09

  The present invention relates to a composition for optical materials, comprising (a) a compound having in one molecule at least one structure represented by the following Formula 1: wherein R1 is a C0-10 hydrocarbon group, each of R2, R3 and R4 is a C1-10 hydrocarbon group or hydrogen, Y is O, S, Se or Te, m is 1 to 5, and n is 0 to 5; (b) a compound having in one molecule at least one isocyanate group and/or at least one isothiocyanate group; (c) a compound having in one molecule at least one mercapto group; and (d) an inorganic compound having sulfur atom and/or selenium atom, and also relates to an optical material produced by polymerization curing the composition, a production method thereof, and an optical lens comprising the optical material. The present invention provides a high refractive, high Abbe's number optical material having an improved impact resistance.

  本发明涉及一种光学材料组合物，包括 (a) 在一个分子中至少有一个结构由下式 1 表示的化合物： 其中 R1 为 C0-10 烃基，R2、R3 和 R4 各为 C1-10 烃基或氢，Y 为 O、S、Se 或 Te，m 为 1 至 5，n 为 0 至 5； (b) 在一个分子中至少具有一个异氰酸酯基团和/或至少一个异硫氰酸酯基团的化合物；(c) 在一个分子中具有至少一个巯基的化合物；以及 (d) 具有硫原子和/或硒原子的无机化合物，还涉及通过聚合固化该组合物生产的光学材料、其生产方法以及包含该光学材料的光学透镜。本发明提供了一种高折射率、高阿贝数的光学材料，具有更好的抗冲击性。
• DIP MOLDED ARTICLE WITH LOW SURFACE RESISTIVITY
  申请人：ZEON CORPORATION

  公开号：EP1595912A1

  公开（公告）日：2005-11-16

  The present invention relates to a dip molding having a low surface resistivity, the dip molding having a surface resistivity that is lower than that of a conventional product even after being washed with superpure water. The dip molding of the present invention has a surface resistivity, measured under an atmosphere of 20°C and a relative humidity of 65%, of 107 to 1010 Ω/square. Since the dip molding of the present invention has a low surface resistivity, it can suitably be used as a glove for precision electronic component production and semiconductor component production.

  本发明涉及一种具有低表面电阻率的浸塑成型件，该浸塑成型件即使在用超纯水冲洗后，其表面电阻率仍低于传统产品的表面电阻率。在 20℃、相对湿度为 65%的环境下测量，本发明的浸塑模具的表面电阻率为 107 至 1010 Ω/平方。由于本发明的浸渍模塑具有较低的表面电阻率，因此可适当用作精密电子元件生产和半导体元件生产的手套。