(1-naphthalenyl)-phenylphosphine | 179117-27-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (1-naphthalenyl)-phenylphosphine
• 英文别名: (1-naphthyl)-phenylphosphonate；1-naphthylphenylphosphine；Phenyl-α-naphthyl-phosphin；Naphthylphenylphosphine；naphthalen-1-yl(phenyl)phosphane
• CAS: 179117-27-2
• 化学式: C₁₆H₁₃P
• 分子量: 236.253
• InChiKey: DNMUKQULDTZTPX-UHFFFAOYSA-N

物化性质

• 沸点：
  376.3±15.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (1-naphthalenyl)-phenylphosphine 在 palladium diacetate 、 sulfur 作用下， 以 氯仿 为溶剂， 反应 2.25h， 生成 4-[Naphthalen-1-yl(phenyl)phosphinothioyl]oxy-2,5-diphenylphenol
  参考文献：
  名称：

  Asymmetric Synthesis of P-Stereogenic Diarylphosphinites by Palladium-Catalyzed Enantioselective Addition of Diarylphosphines to Benzoquinones

  摘要：

  The reaction of phenyl(2,4,6-trimethylphenyl)phosphine with a substituted benzoquinone in the presence of a chiral phosphapalladacycle complex as a catalyst and triethylamine in chloroform at -45 degrees C proceeded in a new type of addition manner to give a high yield of a 4-hydroxyphenyl phenyl(2,4,6-trimethylphenyl)phosphinite with 98% enantioselectivity, which is a versatile intermediate readily convertible into various phosphines and their derivatives with high enantiomeric purity.

  DOI：

  10.1021/ja501007t
• 作为产物：
  描述：

  二氯(萘-1-基)膦 在 盐酸 、 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 生成 (1-naphthalenyl)-phenylphosphine
  参考文献：
  名称：

  含2-芳基恶唑啉的手性磷，硫和硒的制备

  摘要：

  由市售或合成的氨基醇制备一系列对映体纯的2- [2-（二芳基膦基）芳基]-恶唑啉。对于恶唑啉的形成，采用了三种程序：（i）与2-卤代苯甲酸一锅缩合，（ii）ZnCl 2与2-卤代苯甲腈-苯胺催化缩合，和（iii）通过2-卤代苯甲酰胺的三步顺序和甲苯磺酸盐或氯化物。通过非对映选择性亲核取代Ar 1 Ar 2 PC1的卤化物或通过LiPAr 1 Ar 2亲核芳族取代制备含有立体异构磷的膦恶唑啉。另外，制备了硫和硒类似物。

  DOI：

  10.1016/0040-4020(96)00267-0

文献信息

• An Expedient Reduction of<i>sec</i>-Phosphine Oxides to<i>sec</i>-Phosphine-boranesby BH₃˙SMe₂
  作者：K. Michał Pietrusiewicz、Marek Stankevič

  DOI：10.1055/s-2003-39304

  日期：——

  Secondary phosphine oxides can be expeditiously converted into secondary phosphine-boranes by treatment with an excess of BH3˙SMe2 at room temperature. Selectivity of the conversion towards the formation of secondary phosphine-boranes is greatly improved by the addition of a small amount of water to the reaction mixture.

  次级磷氧化物可以通过在室温下用过量的BH3·SMe2处理迅速转化为次级磷硼烷。向反应混合物中加入少量水可以显著提高生成次级磷硼烷的转化选择性。
• Syntheses of New Chiral Phosphane Ligands by Diastereoselective Conjugate Addition of Phosphides to Enantiomerically Pure Acceptor-Substituted Olefins from the Chiral Pool
  作者：Burkhard Wiese、Guido Knühl、Dietmar Flubacher、Jan W. Prieß、Bolette Ulriksen (nee Laursen)、Kerstin Brödner、Günter Helmchen

  DOI：10.1002/ejoc.200500144

  日期：2005.8

  compounds and related acceptor-substituted olefins derived from myrtenal as ex chiral pool source. Monophosphanes with astereogenic as well as stereogenic phosphorus are described. In addition diphosphanes were prepared by a highly diastereoselective double conjugate addition of a secondary diphosphane. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

  通过将膦以高度非对映选择性加成到 α,β-不饱和羰基化合物和衍生自桃金娘烯醛的相关受体取代烯烃作为手性池源，制备了多种新型手性膦。描述了具有立体生成和立体生成磷的 Monophosphanes。此外，二膦是通过高度非对映选择性双共轭加成仲二膦制备的。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
• Phosphorus substituted metallocene compounds for olefin polymerization
  申请人：Voskoboynikov Z. Alexander

  公开号：US20050239980A1

  公开（公告）日：2005-10-27

  This invention relates to a metallocene compounds represented by formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is an indenyl ligand that is substituted with a PR 2 group in the two position of the indenyl ligand, where each R is, independently a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl substituent, and additionally, E may be substituted with 0, 1, 2, 3, 4, 5 or 6 R n where each R n is, independently, a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent, and optionally, two or more adjacent R n substituents may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E or as X; each X is, independently, an univalent anionic ligand, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.

  本发明涉及一种由以下公式表示的金属茂化合物：其中M是3、4、5或6族过渡金属原子、镧系金属原子或锕系金属原子；E是一个在茂环的2位被PR2基取代的茚烯配体，其中每个R都是独立的，可以是一个碳氢化合物、取代的碳氢化合物、卤代碳氢化合物或取代的卤代碳氢化合物基团，此外，E可以被0、1、2、3、4、5或6个Rn取代，其中每个Rn都是独立的，可以是一个碳氢化合物、取代的碳氢化合物、卤代碳氢化合物、取代的卤代碳氢化合物、硅基碳氢化合物、取代的硅基碳氢化合物、锗基碳氢化合物或取代的锗基碳氢化合物基团，而且，两个或更多相邻的Rn取代基团可以结合在一起形成取代或未取代的饱和、部分不饱和或芳香环或多环取代基团；A是一个取代或未取代的环戊二烯基配体、取代或未取代的杂环戊二烯基配体、取代或未取代的茚烯配体、取代或未取代的杂茚烯配体、取代或未取代的芴基配体、取代或未取代的杂芴基配体或其他单阴离子配体，或者A可以独立地被定义为E或X；每个X都是独立的一价阴离子配体，或者两个X结合并与金属原子结合形成金属环烷基，或两个X结合形成螯合配体、二烯配体或烷基亚胺配体。
• HETEROCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING ELEMENT USING SAME
  申请人：LG Chem, Ltd.

  公开号：EP3053984A1

  公开（公告）日：2016-08-10

  The present specification provides a heterocyclic compound and an organic light emitting device using the same.

  本说明书提供了一种杂环化合物和使用该杂环化合物的有机发光器件。
• Flame retardant epoxy prepregs, laminates, and printed wiring boards of enhanced thermal stability
  申请人：Ranken F. Paul

  公开号：US20050075024A1

  公开（公告）日：2005-04-07

  Boehmite (alumina monohydrate) when used with a typical epoxy resin advanced with phosphorus makes it possible to improve thermal stability and to increase the ignition time of laminates formed from prepregs made using this fortified resin. Such laminates have exceptionally high thermal stability and showed similar longer times to ignition as compared to corresponding resins in which alumina trihydrate was used.

  将波美度石（一水合氧化铝）与添加了磷的典型环氧树脂一起使用，可以提高热稳定性，并延长使用这种强化树脂制成的预浸料层压板的点火时间。这种层压板具有极高的热稳定性，与使用三水氧化铝的相应树脂相比，点火时间同样更长。