N-[bis(dimethylamino)phosphanyl]-N-methylmethanamine;carbon monoxide;iron | 19372-47-5

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: N-[bis(dimethylamino)phosphanyl]-N-methylmethanamine;carbon monoxide;iron
• CAS: 19372-47-5；40697-04-9
• 化学式: C₁₀H₁₈FeN₃O₄P
• 分子量: 331.091
• InChiKey: RMGYLHZRPMPOPS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  N-[bis(dimethylamino)phosphanyl]-N-methylmethanamine;carbon monoxide;iron 以 四氢呋喃 、 正戊烷 为溶剂， 生成
  参考文献：
  名称：

  First aminosilyl bridging ligand in a bimetallic complex: structure of [(OC)₃{(Me₂N)₂(MeO)P}Fe{µ-Si(OMe)₂(NMe₂)}Cu(PPh₃)]

  摘要：

  The first example of a bridging aminosilyl ligand between two transition metals is reported and the crystal structure of the bimetallic complex [(OC)(3){(Me(2)N)(2)(MeO)P}Fe{mu-Si(OMe)(2)(NMe(2))}Cu(PPh(3))] establishes the presence of an unprecedented four-membered cycle; selective metal-promoted OMe/NMe(2) substituent exchange between P and Si occurs-during the synthesis of the iron-silylene precursor.

  DOI：

  10.1039/cc9960002237
• 作为产物：
  描述：

  五羰基铁 、 三(二甲胺基)膦 以 neat (no solvent) 为溶剂， 生成 N-[bis(dimethylamino)phosphanyl]-N-methylmethanamine;carbon monoxide;iron
  参考文献：
  名称：

  Inoue, Hidenary; Nakagome, Takashi; Kuroiwa, Takeshi, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1987, vol. 42, # 5, p. 573 - 578

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Fe: Org.Verb.B1, 1.1.4.4.3.1, page 148 - 168
  作者：

  DOI：——

  日期：——
• Phosphorus-31-phosphorus-31 coupling in metal complexes containing two different phosphorus ligands
  作者：F. B. Ogilvie、R. L. Keiter、G. Wulfsberg、J. G. Verkade

  DOI：10.1021/ic50081a024

  日期：1969.11
• Cowley, Alan H.; Davis, Raymond E.; Remadna, Khier, Inorganic Chemistry, 1981, vol. 20, # 7, p. 2146 - 2152
  作者：Cowley, Alan H.、Davis, Raymond E.、Remadna, Khier

  DOI：——

  日期：——
• Thiocarbonyl complexes of iron: formation of dinuclear compounds by the phosphine-induced CO-CS coupling in the reaction of Fe(CO)4CS with P(NMe2)3. Molecular structure of Fe2(CO)6S2COCP(NMe2)3
  作者：Wolfgang Petz、Frank Weller

  DOI：10.1021/om00034a044

  日期：1993.10

  Slow addition of Fe(CO)4CS to an excess of P(NMe2)3 affords the dinuclear complexes Fe2(CO)6S2COCP(NMe2)3 (1) and Fe2(CO)5(P(NMe2)3)S2COCP(NMe2)3 (2), the mononuclear complex (Fe(CO)2(P(NMe2)3)S2COCP(NMe2)3(3), and the sulfur transfer product S=P(NMe2)3 (4). The iron compounds contain a new betaine-like ligand which is composed of P(NMe2)3, CS, CO, and an additional S atom and bonded to the iron atoms via the sulfur atoms: C-C bond formation between the CS group and one CO ligand has occurred. Complex 1 crystallizes in the space group Pbca with cell parameters a = 1513.3(3) pm, b = 1324.3(1) pm, c = 2278.4(2) pm, and Z = 8. The dinuclear compounds 1 and 2 have a butterfly structure, and the ligand acts as a six-electron donor. P-31, C-13, and H-1 NMR and IR spectra are in accord with the structures.
• Inoue, Hidenary; Nakagome, Takashi; Kuroiwa, Takeshi, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1987, vol. 42, # 5, p. 573 - 578
  作者：Inoue, Hidenary、Nakagome, Takashi、Kuroiwa, Takeshi、Shirai, Tsuneo、Fluck, Ekkehard

  DOI：——

  日期：——

表征谱图