CH2=CH(CH2)6N(CH3)2 | 16083-54-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: CH2=CH(CH2)6N(CH3)2
• 英文别名: 8-Dimethylaminoocten；N,N-dimethyloct-7-en-1-amine
• CAS: 16083-54-8
• 化学式: C₁₀H₂₁N
• mdl: MFCD09836807
• 分子量: 155.283
• InChiKey: KWHNJSMJWDZDKD-UHFFFAOYSA-N

物化性质

• 沸点：
  65.5-66.0 °C(Press: 11 Torr)
• 密度：
  0.792±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  CH2=CH(CH2)6N(CH3)2 、 对溴苯甲醛 在 2,2,6,6-四甲基哌啶 、 三氟化硼乙醚 、 C₂₆H₃₃FeO₄⁽¹⁺⁾*BF₄^(1-) 作用下， 以 甲苯 为溶剂， 以68 %的产率得到1-(4-bromophenyl)-7-(dimethylamino)-2-vinylheptan-1-ol
  参考文献：
  名称：

  设计用于丙烯和简单烯烃烯丙基 C−H 官能化的铁催化剂

  摘要：

  发现了一种新的环戊二烯基铁二羰基络合物，可以使丙烯的烯丙基碳与羰基亲电子试剂偶联。该方法还成功应用于简单烯烃的烯丙基 C−H 官能化。实验和计算研究提供了配体对反应性和非对映选择性影响的机制和起源的见解。

  DOI：

  10.1002/anie.202216309
• 作为产物：
  描述：

  N-methylazacyclononane 以 甲醇 、 苯 为溶剂， 生成 CH2=CH(CH2)6N(CH3)2
  参考文献：
  名称：

  Structural and mechanistic effects on the rates of ring-opening reactions in the 5-16-membered-ring region

  摘要：

  DOI：

  10.1021/jo01308a002

文献信息

• Halogen substituted metallocene compounds for olefin polymerization
  申请人：Voskoboynikov Z. Alexander

  公开号：US20070135594A1

  公开（公告）日：2007-06-14

  A metallocene compound is represented by the formula (1): AMX n-1 wherein M is a transition metal atom having a coordination number of n selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom; A is a substituted monocyclic or polycyclic arenyl ligand pi-bonded to M, wherein said arenyl ligand includes at least one halogen substituent directly bonded to any sp 2 carbon atom at a bondable ring position of the ligand; and the or each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand.

  一种金属烯化合物可以用公式(1)表示： AMX n-1 其中，M是具有配位数n的过渡金属原子，选自元素周期表第3、4、5或6族，或为镧系金属原子，或锕系金属原子；A是与M以π键结合的取代的单环或多元环芳基配体，其中所述芳基配体包括至少一个直接键合到配体的可键合环位上的任意sp2碳原子上的卤素取代基；而X是单价阴离子配体，或者两个X连接并与金属原子结合形成一个金属环烯环，或者两个X连接形成一个螯合配体、二烯配体或烷基亚烯配体。
• [EN] TRANSITION METAL COMPOUNDS FOR OLEFIN POLYMERIZATION AND OLIGOMERIZATION<br/>[FR] COMPOSES METALLIQUES DE TRANSITION POUR LA POLYMERISATION D'OLEFINES ET L'OLIGOMERISATION
  申请人：EXXONMOBIL CHEM PATENTS INC

  公开号：WO2005118605A1

  公开（公告）日：2005-12-15

  This invention relates to new transition metal catalyst compounds represented by the formula (I): where: M and M' are, independently, a group 8, 9, 10 or 11 transition metal, preferably Ni, Co, Pd, Cu or Fe; each R group is, independently, is, hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; R' is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together with R' to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; each X group is, independently, is, hydrogen, a halogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted sililcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent X groups may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; m and m’ are, independently, 0, 1, 2, or 3; z and z’ are, independently, 0, 1, 2, or 3; N is nitrogen; Q is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents; Q’ is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl or substituted germylcarbyl substituents; and L is a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent.

  这项发明涉及由式(I)表示的新过渡金属催化剂化合物，其中：M和M'分别是8、9、10或11族过渡金属，优选为Ni、Co、Pd、Cu或Fe；每个R基分别是氢，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基，且可选地，相邻的R基可以结合在一起形成取代或未取代的饱和、部分不饱和或芳香环或多环取代基；R'是氢，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基，且可选地，相邻的R基可以与R'结合在一起形成取代或未取代的饱和、部分不饱和或芳香环或多环取代基；每个X基分别是氢，卤素，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基，且可选地，相邻的X基可以结合在一起形成取代或未取代的饱和、部分不饱和或芳香环或多环取代基；m和m'分别为0、1、2或3；z和z'分别为0、1、2或3；N为氮；Q为氢，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基；Q'为氢，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基；L为烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基。
• Heteroatom bridged metallocene compounds for olefin polymerization
  申请人：Voskoboynikov Z. Alexander

  公开号：US20070135597A1

  公开（公告）日：2007-06-14

  This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand. This invention further relates to catalyst systems comprising the above transiotioon metal compounds, activators and optional supports and their use to polymerize or oligomerize olefins.

  本发明涉及一种过渡金属化合物，其表示为以下公式：其中M是3、4、5或6族过渡金属原子，或镧系金属原子，或锕系金属原子；E是：1）与Y通过茚环的四、五、六或七位置结合的取代或未取代的茚基配体，或2）与Y通过杂环茚环的四、五或六位置结合的取代或未取代的杂环茚基配体，前提是结合位置与环杂原子的位置不同，或3）与Y通过芴环的一、二、三、四、五、六、七或八位置结合的取代或未取代的芴基配体，或4）与Y通过杂芴环的一、二、三、四、五或六位置结合的取代或未取代的杂芴基配体，前提是结合位置与环杂原子的位置不同；A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂环茚基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体，或其他单阴离子配体；Y是通过杂原子与E和A结合的15族或16族桥接杂原子取代基；X是独立的一价阴离子配体，或两个X结合并与金属原子结合形成金属环，或两个X结合形成螯合配体、二烯基配体或烷基亚基配体。本发明还涉及包含上述过渡金属化合物、活化剂和可选支撑物的催化剂系统及其用于聚合或寡聚烯烃的用途。
• Preparation of substituted bridged indenyl and related ligands
  申请人：Voskoboynikov Z. Alexander

  公开号：US20070135596A1

  公开（公告）日：2007-06-14

  A process for preparing a chelating ligand of the formula (II) from a chelating ligand of the formula (I) via an sp 2 -sp 2 or sp 2 -sp 3 coupling reaction with an organometallic compound of the formula (III). wherein B is a bridging group that is bonded to L 1 and L 2 in formula (I) and to L 3 and L 4 in formula (II); L 1 is a substituted monocyclic or polycyclic ligand that comprises at least one chlorine, bromine, iodine, or sulfonate substituent, directly bonded to an sp 2 carbon atom of the ring structure of the ligand; L 2 is a monoanionic ligand; or L 2 may, independently, be defined as L 1 ; L 3 is the same group as L 1 , but said at least one chlorine, bromine, iodine, or sulfonate substituent is replaced with a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl fragment; L 4 is the same group as L 2 , though, when L 2 is defined as L 1 , L 4 may be the same as L 3 or L 1 ; R 1 is a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl; M 1 is an element of group 1, 2, 12, 13 or 14 of the Periodic Table of the Elements; each X 2 , if present, is selected independently from the group consisting of halogen atoms, the hydroxyl group, alkoxy groups, aryloxy groups, mesylate, tosylate and triflate; r is 1, 2 or 3, and t is 0, 1 or 2, where r+t corresponds to the oxidation number of M 1 .

  从化学配体的公式(I)通过与公式(III)的有机金属化合物进行sp2-sp2或sp2-sp3偶联反应，制备化学配体的公式(II)的方法。其中B是一个桥联基团，与公式(I)中的L1和L2以及公式(II)中的L3和L4结合；L1是一个取代的单环或多环配体，至少包含一个氯、溴、碘或磺酸酯取代基，直接与配体的环结构的sp2碳原子键合；L2是一个单负离子配体；或者L2可以独立地被定义为L1；L3与L1相同，但所述的至少一个氯、溴、碘或磺酸酯取代基被氢化碳基、取代的氢化碳基、卤代碳基或取代的卤代碳基片段所取代；L4与L2相同，但当L2被定义为L1时，L4可以与L3或L1相同；R1是一个氢化碳基、取代的氢化碳基、卤代碳基或取代的卤代碳基；M1是元素周期表第1、2、12、13或14组的元素；每个X2，如果存在，可独立地选择自卤素原子、羟基、烷氧基、芳基氧基、甲磺酸酯、对甲苯磺酸酯和三氟甲磺酸酯组成的群；r为1、2或3，t为0、1或2，其中r+t对应于M1的氧化数。
• Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
  申请人：Voskoboynikov Z. Alexander

  公开号：US20070135623A1

  公开（公告）日：2007-06-14

  Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp 2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.

  描述了卤代取代的茂金属化合物，包括一个或多个与金属原子π键结合的单环或多环配体，并且至少包括一个卤素取代基直接键合到配体的可键合环位置上的sp2碳原子，其中该配体或至少一个配体在其环状结构中具有一个或多个环异原子。与适当的活化剂结合时，这些化合物在烯烃聚合反应中显示出活性，例如乙烯和丙烯。